! W. K. METCALFE, S. DOOLEY, H. J. CURRAN, J. M. SIMMIE, A. EL-NAHAS, M. V. NAVARRO ! 'AN EXPERIMENTAL AND MODELING STUDY OF C5H10O2 ETHYL AND METHYL ESTERS' ! SUBMITTED TO J.PHYS.CHEM 15/11/06 ELEMENTS C H N O AR HE !TO MODIFY END SPECIES H H2 CH3CO CH2OCHO MB O CH2CHO HE MB2D O2 CH2CO C3H8 MB2J OH HCCO IC3H7 MB2O H2O HCCOH NC3H7 MB2OH3J N2 CH3CO3H C3H6 MB2OH3OO HO2 CH3CO3 C3H5-A MB3D H2O2 CH3CO2 C3H5-S MB3J AR C2H5OH C3H5-T MB3O CO C2H5O C3H4-P MB3OH4J CO2 PC2H4OH C3H4-A MB3OH4OO CH2O SC2H4OH C3H3 MB4*O HCO O2C2H4OH C3H2 MB4J HO2CHO C2H5O2H C3H5O MB4O O2CHO C2H5O2 C3H6OOH1-2 MBM*O HOCHO C2H4O2H C3H6OOH1-3 MBMJ OCHO C2H4O1-2 C3H6OOH2-1 MBMJ*O HOCH2O2H C2H3O1-2 C3H6OOH1-2O2 MBMO HOCH2O2 CH3COCH3 C3H6OOH1-3O2 ME2*O OCH2O2H CH3COCH2 C3H6OOH2-1O2 ME2J HOCH2O CH3COCH2O2 C3H6OOH2-2 MP2D CH3OH CH3COCH2O2H NC3H7O2H MP2D3J CH2OH CH3COCH2O IC3H7O2H MP2OH3J CH3O C2H3CHO NC3H7O2 MP2OH3OO CH3O2H C2H3CO IC3H7O2 MP3*O CH3O2 C2H5CHO NC3H7O MP3J CH4 C2H5CO IC3H7O CH2CHCHCO CH3 CH3OCH3 C3H6O1-2 CHOOCO CH2 CH3OCH2 C3H6O1-3 C2H5CHCO CH2(S) CH3OCH2O2 C3KET12 BAOJ C CH2OCH2O2H C3KET13 C5H7O2 CH CH3OCH2O2H C3KET21 NC3H7CO C2H6 CH3OCH2O C3H51-2,3OOH CJHCHCHCO C2H5 O2CH2OCH2O2H C3H52-1,3OOH CH3CHCHO C2H4 HO2CH2OCHO C3H6OH CH3COOCH3 C2H3 OCH2OCHO HOC3H6O2 C2H2 HOCH2OCO CH3CHCO C2H CH3OCHO AC3H5OOH CH3CHO CH3OCO C2H3OOH END REACTIONS H+O2<=>O+OH 1.915E+14 0.00 1.644E+04 REV/ 5.481E+11 0.39 -2.930E+02 / O+H2<=>H+OH 5.080E+04 2.67 6.292E+03 REV/ 2.667E+04 2.65 4.880E+03 / OH+H2<=>H+H2O 2.160E+08 1.51 3.430E+03 REV/ 2.298E+09 1.40 1.832E+04 / O+H2O<=>OH+OH 2.970E+06 2.02 1.340E+04 REV/ 1.465E+05 2.11 -2.904E+03 / H2+M<=>H+H+M 4.577E+19 -1.40 1.044E+05 REV/ 1.146E+20 -1.68 8.200E+02 / H2/2.5/ H2O/12/ CO/1.9/ CO2/3.8/ O2+M<=>O+O+M 4.515E+17 -0.64 1.189E+05 REV/ 6.165E+15 -0.50 0.000E+00 / H2/2.5/ H2O/12/ AR/.83/ CO/1.9/ CO2/3.8/ CH4/2/ C2H6/3/ HE/.83/ OH+M<=>O+H+M 9.880E+17 -0.74 1.021E+05 REV/ 4.714E+18 -1.00 0.000E+00 / H2/2.5/ H2O/12/ AR/.75/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.75/ H2O+M<=>H+OH+M 1.912E+23 -1.83 1.185E+05 REV/ 4.500E+22 -2.00 0.000E+00 / H2/.73/ H2O/12/ AR/.38/ CH4/2/ C2H6/3/ HE/.38/ H+O2(+M)<=>HO2(+M) 1.475E+12 0.60 0.000E+00 !REV/ 3.090E+12 0.53 4.887E+04 / LOW / 3.4820E+16 -4.1100E-01 -1.1150E+03 / TROE / 5.0000E-01 1.0000E-30 1.0000E+30 1.0000+100 / !TROE FALL-OFF REACTION H2/1.3/ H2O/14/ AR/.67/ CO/1.9/ CO2/3.8/ CH4/2/ C2H6/3/ HE/.67/ HO2+H<=>H2+O2 1.660E+13 0.00 8.230E+02 REV/ 3.164E+12 0.35 5.551E+04 / HO2+H<=>OH+OH 7.079E+13 0.00 2.950E+02 REV/ 2.027E+10 0.72 3.684E+04 / HO2+O<=>OH+O2 3.250E+13 0.00 0.000E+00 REV/ 3.252E+12 0.33 5.328E+04 / HO2+OH<=>H2O+O2 2.890E+13 0.00 -4.970E+02 REV/ 5.861E+13 0.24 6.908E+04 / H2O2+O2<=>HO2+HO2 4.634E+16 -0.35 5.067E+04 REV/ 4.200E+14 0.00 1.198E+04 / DUP H2O2+O2<=>HO2+HO2 1.434E+13 -0.35 3.706E+04 REV/ 1.300E+11 0.00 -1.629E+03 / DUP H2O2(+M)<=>OH+OH(+M) 2.951E+14 0.00 4.843E+04 !REV/ 3.656E+08 1.14 -2.584E+03 / LOW / 1.2020E+17 0.0000E+00 4.5500E+04 / TROE / 5.0000E-01 1.0000E-30 1.0000E+30 1.0000+100 / !TROE FALL-OFF REACTION H2/2.5/ H2O/12/ AR/.64/ CO/1.9/ CO2/3.8/ CH4/2/ C2H6/3/ HE/.64/ H2O2+H<=>H2O+OH 2.410E+13 0.00 3.970E+03 REV/ 1.269E+08 1.31 7.141E+04 / H2O2+H<=>H2+HO2 6.025E+13 0.00 7.950E+03 REV/ 1.041E+11 0.70 2.395E+04 / H2O2+O<=>OH+HO2 9.550E+06 2.00 3.970E+03 REV/ 8.660E+03 2.68 1.856E+04 / H2O2+OH<=>H2O+HO2 1.000E+12 0.00 0.000E+00 REV/ 1.838E+10 0.59 3.089E+04 / DUP H2O2+OH<=>H2O+HO2 5.800E+14 0.00 9.557E+03 REV/ 1.066E+13 0.59 4.045E+04 / DUP CO+O(+M)<=>CO2(+M) 1.800E+10 0.00 2.384E+03 !REV/ 9.980E+15 -0.94 1.300E+05 / LOW / 1.3500E+24 -2.7880E+00 4.1910E+03 / !LINDEMANN FALL-OFF REACTION H2/2/ O2/6/ H2O/6/ AR/.5/ CO/1.5/ CO2/3.5/ CH4/2/ C2H6/3/ HE/.5/ CO+O2<=>CO2+O 1.050E+12 0.00 4.254E+04 REV/ 7.950E+15 -0.80 5.123E+04 / CO+OH<=>CO2+H 1.400E+05 1.95 -1.347E+03 REV/ 3.704E+11 0.76 2.408E+04 / CO+HO2<=>CO2+OH 3.010E+13 0.00 2.300E+04 REV/ 2.280E+16 -0.47 8.497E+04 / HCO+M<=>H+CO+M 1.860E+17 -1.00 1.700E+04 REV/ 1.403E+16 -0.62 1.670E+03 / H2/2/ H2O/12/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HCO+O2<=>CO+HO2 2.710E+10 0.68 -4.690E+02 REV/ 4.283E+09 0.99 3.307E+04 / HCO+H<=>CO+H2 7.340E+13 0.00 0.000E+00 REV/ 2.211E+12 0.66 8.823E+04 / HCO+O<=>CO+OH 3.020E+13 0.00 0.000E+00 REV/ 4.775E+11 0.64 8.682E+04 / HCO+O<=>CO2+H 3.000E+13 0.00 0.000E+00 REV/ 1.255E+18 -0.55 1.122E+05 / HCO+OH<=>CO+H2O 1.020E+14 0.00 0.000E+00 REV/ 3.269E+13 0.55 1.031E+05 / HCO+CH3<=>CH4+CO 2.650E+13 0.00 0.000E+00 REV/ 7.286E+14 0.21 8.977E+04 / HCO+HO2<=>CH2O+O2 2.499E+14 -0.06 1.392E+04 REV/ 8.070E+15 0.00 5.342E+04 / HCO+HO2<=>CO2+H+OH 3.000E+13 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / O2CHO<=>HCO+O2 1.396E+29 -4.55 4.630E+04 REV/ 1.200E+11 0.00 -1.100E+03 / CH2O+O2CHO<=>HCO+HO2CHO 1.990E+12 0.00 1.166E+04 REV/ 3.744E+03 1.95 7.145E+03 / HO2CHO<=>OCHO+OH 5.010E+14 0.00 4.015E+04 REV/ 2.871E+06 2.09 -7.012E+03 / OCHO+M<=>H+CO2+M 5.315E+14 -0.35 1.758E+04 REV/ 7.500E+13 0.00 2.900E+04 / CH2O+CO<=>HCO+HCO 9.186E+13 0.37 7.304E+04 REV/ 1.800E+13 0.00 0.000E+00 / HCO+HCO<=>H2+CO+CO 3.000E+12 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / HCO+H(+M)<=>CH2O(+M) 1.090E+12 0.48 -2.600E+02 !REV/ 7.373E+13 0.47 8.811E+04 / LOW / 1.3500E+24 -2.5700E+00 1.4250E+03 / TROE / 7.8240E-01 2.7100E+02 2.7550E+03 6.5700E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ CO+H2(+M)<=>CH2O(+M) 4.300E+07 1.50 7.960E+04 !REV/ 9.656E+10 0.83 7.974E+04 / LOW / 5.0700E+27 -3.4200E+00 8.4348E+04 / TROE / 9.3200E-01 1.9700E+02 1.5400E+03 1.0300E+04 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ CH2O+OH<=>HCO+H2O 7.820E+07 1.63 -1.055E+03 REV/ 4.911E+06 1.81 2.903E+04 / CH2O+H<=>HCO+H2 5.740E+07 1.90 2.740E+03 REV/ 3.388E+05 2.19 1.793E+04 / CH2O+O<=>HCO+OH 6.260E+09 1.15 2.260E+03 REV/ 1.940E+07 1.42 1.604E+04 / CH2O+CH3<=>HCO+CH4 3.830E+01 3.36 4.312E+03 REV/ 2.063E+02 3.20 2.104E+04 / CH2O+HO2<=>HCO+H2O2 7.100E-03 4.52 6.580E+03 REV/ 2.426E-02 4.11 5.769E+03 / HOCH2O<=>CH2O+OH 2.056E+21 -2.34 2.573E+04 REV/ 4.500E+15 -1.10 0.000E+00 / HOCH2O<=>HOCHO+H 1.000E+14 0.00 1.490E+04 REV/ 1.123E+15 -0.30 1.150E+04 / HOCHO<=>CO+H2O 2.300E+13 0.00 5.000E+04 REV/ 2.124E+04 2.09 4.242E+04 / HOCHO<=>CO2+H2 1.500E+16 0.00 5.700E+04 REV/ 2.399E+14 0.46 6.102E+04 / HOCHO<=>HCO+OH 3.471E+22 -1.54 1.107E+05 REV/ 1.000E+14 0.00 0.000E+00 / HOCHO+O2<=>OCHO+HO2 4.101E+12 -0.31 5.988E+04 REV/ 3.500E+10 0.00 -3.275E+03 / HOCHO+OH<=>H2O+CO2+H 2.620E+06 2.06 9.160E+02 REV/ 0.000E+00 0.00 0.000E+00 / HOCHO+OH<=>H2O+CO+OH 1.850E+07 1.51 -9.620E+02 REV/ 0.000E+00 0.00 0.000E+00 / HOCHO+H<=>H2+CO2+H 4.240E+06 2.10 4.868E+03 REV/ 0.000E+00 0.00 0.000E+00 / HOCHO+H<=>H2+CO+OH 6.030E+13 -0.35 2.988E+03 REV/ 0.000E+00 0.00 0.000E+00 / HOCHO+CH3<=>CH4+CO+OH 3.900E-07 5.80 2.200E+03 REV/ 0.000E+00 0.00 0.000E+00 / HOCHO+HO2<=>OCHO+H2O2 2.549E+12 0.04 3.447E+04 REV/ 2.400E+12 0.00 1.000E+04 / HOCHO+HO2<=>H2O2+CO+OH 1.000E+12 0.00 1.192E+04 REV/ 0.000E+00 0.00 0.000E+00 / HOCHO+O<=>CO+OH+OH 1.770E+18 -1.90 2.975E+03 REV/ 0.000E+00 0.00 0.000E+00 / HOCHO+HCO<=>CH2O+OCHO 8.584E+11 0.04 2.675E+04 REV/ 5.600E+12 0.00 1.360E+04 / CH3O(+M)<=>CH2O+H(+M) 6.800E+13 0.00 2.617E+04 !REV/ 1.049E+12 0.39 3.878E+03 / LOW / 1.8670E+25 -3.0000E+00 2.4307E+04 / TROE / 9.0000E-01 2.5000E+03 1.3000E+03 1.0000E+99 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ CH3O+O2<=>CH2O+HO2 4.380E-19 9.50 -5.501E+03 REV/ 1.416E-20 9.82 2.108E+04 / CH2O+CH3O<=>CH3OH+HCO 6.620E+11 0.00 2.294E+03 REV/ 8.393E+10 0.07 1.771E+04 / CH4+CH3O<=>CH3+CH3OH 6.119E+02 2.87 8.248E+03 REV/ 1.440E+01 3.10 6.935E+03 / CH3O+CH3<=>CH2O+CH4 1.200E+13 0.00 0.000E+00 REV/ 6.749E+13 0.22 8.281E+04 / CH3O+H<=>CH2O+H2 2.000E+13 0.00 0.000E+00 REV/ 1.232E+11 0.66 8.127E+04 / CH3O+HO2<=>CH2O+H2O2 3.010E+11 0.00 0.000E+00 REV/ 1.074E+12 -0.03 6.527E+04 / CH2O+H(+M)<=>CH2OH(+M) 5.400E+11 0.45 3.600E+03 !REV/ 8.649E+12 -0.04 3.241E+04 / LOW / 1.2700E+32 -4.8200E+00 6.5300E+03 / TROE / 7.1870E-01 1.0300E+02 1.2910E+03 4.1600E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ CH2OH+O2<=>CH2O+HO2 1.510E+15 -1.00 0.000E+00 REV/ 1.975E+14 -0.58 2.006E+04 / DUP CH2OH+O2<=>CH2O+HO2 2.410E+14 0.00 5.017E+03 REV/ 3.152E+13 0.42 2.508E+04 / DUP CH2OH+H<=>CH2O+H2 6.000E+12 0.00 0.000E+00 REV/ 1.496E+11 0.77 7.475E+04 / CH2OH+HO2<=>CH2O+H2O2 1.200E+13 0.00 0.000E+00 REV/ 1.732E+14 0.07 5.875E+04 / CH2OH+HCO<=>CH2O+CH2O 1.800E+14 0.00 0.000E+00 REV/ 7.602E+14 0.48 5.956E+04 / CH2OH+CH3O<=>CH2O+CH3OH 2.400E+13 0.00 0.000E+00 REV/ 1.285E+13 0.56 7.498E+04 / CH2OH+CH2O<=>CH3OH+HCO 1.878E+04 2.72 4.208E+03 REV/ 9.630E+03 2.90 1.311E+04 / OH+CH2OH<=>H2O+CH2O 2.400E+13 0.00 0.000E+00 REV/ 6.366E+12 0.66 8.964E+04 / O+CH2OH<=>OH+CH2O 4.200E+13 0.00 0.000E+00 REV/ 5.496E+11 0.75 7.334E+04 / CH2O+CH3OH<=>CH2OH+CH2OH 6.498E+12 0.66 6.846E+04 REV/ 3.000E+12 0.00 0.000E+00 / CH2OH+HO2<=>HOCH2O+OH 1.000E+13 0.00 0.000E+00 REV/ 8.169E+13 -0.02 3.347E+04 / OCH2O2H<=>CH2O+HO2 1.278E+18 -1.80 1.046E+04 REV/ 1.500E+11 0.00 1.190E+04 / OCH2O2H<=>HOCH2O2 3.000E+11 0.00 8.600E+03 REV/ 4.241E+08 0.95 2.620E+04 / HOCH2O2+HO2<=>HOCH2O2H+O2 3.500E+10 0.00 -3.275E+03 REV/ 1.046E+14 -0.84 3.487E+04 / HOCH2O2H<=>HOCH2O+OH 1.023E+21 -1.92 4.249E+04 REV/ 1.000E+13 0.00 0.000E+00 / CH3OH(+M)<=>CH3+OH(+M) 1.900E+16 0.00 9.173E+04 !REV/ 1.025E+11 0.78 -7.520E+02 / LOW / 2.9500E+44 -7.3500E+00 9.5460E+04 / TROE / 4.1400E-01 2.7900E+02 5.4590E+03 1.0000+100 / !TROE FALL-OFF REACTION CH3OH(+M)<=>CH2OH+H(+M) 2.690E+16 -0.08 9.894E+04 !REV/ 7.754E+14 -0.25 1.668E+03 / LOW / 2.3400E+40 -6.3300E+00 1.0310E+05 / TROE / 7.7300E-01 6.9300E+02 5.3330E+03 1.0000+100 / !TROE FALL-OFF REACTION CH3OH+H<=>CH3O+H2 3.600E+12 0.00 6.095E+03 REV/ 1.676E+11 0.21 5.868E+03 / CH3OH+H<=>CH2OH+H2 1.204E+06 2.40 2.583E+03 REV/ 1.386E+04 2.51 8.871E+03 / CH3OH+O<=>CH2OH+OH 3.880E+05 2.50 3.080E+03 REV/ 2.344E+03 2.59 7.956E+03 / CH3OH+OH<=>CH3O+H2O 5.130E+05 2.13 2.450E+03 REV/ 2.541E+05 2.24 1.712E+04 / CH3OH+OH<=>CH2OH+H2O 1.440E+06 2.00 -8.390E+02 REV/ 1.763E+05 2.00 2.034E+04 / CH3OH+O2<=>CH2OH+HO2 2.050E+13 0.00 4.490E+04 REV/ 1.238E+12 -0.24 -3.501E+03 / CH3OH+HO2<=>CH2OH+H2O2 1.080E+04 2.55 1.053E+04 REV/ 7.195E+04 1.96 8.190E+02 / CH3OH+CH3<=>CH2OH+CH4 3.190E+01 3.17 7.172E+03 REV/ 3.351E+02 2.83 1.500E+04 / CH3O+CH3OH<=>CH2OH+CH3OH 3.000E+11 0.00 4.074E+03 REV/ 7.416E+10 -0.10 1.059E+04 / CH3OH+CH2O<=>CH3O+CH3O 7.981E+12 0.45 8.149E+04 REV/ 6.030E+13 0.00 0.000E+00 / CH3+H(+M)<=>CH4(+M) 2.108E+14 0.00 0.000E+00 !REV/ 7.682E+16 -0.17 1.051E+05 / LOW / 6.1650E+23 -1.8000E+00 0.0000E+00 / TROE / 3.7000E-01 3.3150E+03 6.1000E+01 1.0000E+99 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ CH4+H<=>CH3+H2 6.140E+05 2.50 9.587E+03 REV/ 6.727E+02 2.95 8.047E+03 / CH4+OH<=>CH3+H2O 5.830E+04 2.60 2.190E+03 REV/ 6.796E+02 2.94 1.554E+04 / CH4+O<=>CH3+OH 4.396E+05 2.50 6.577E+03 REV/ 2.528E+02 2.93 3.625E+03 / CH4+HO2<=>CH3+H2O2 6.776E+04 2.50 2.100E+04 REV/ 4.297E+04 2.25 3.462E+03 / CH4+CH2<=>CH3+CH3 2.460E+06 2.00 8.270E+03 REV/ 1.088E+03 2.74 1.057E+04 / CH3+OH<=>CH2O+H2 3.190E+09 0.00 5.027E+03 REV/ 4.249E+11 -0.18 7.499E+04 / CH3+OH<=>CH2(S)+H2O 6.440E+17 -1.34 1.417E+03 REV/ 2.371E+16 -0.86 1.039E+03 / CH3+OH<=>CH3O+H 7.226E+11 0.00 5.484E+03 REV/ 1.562E+16 -0.84 -5.821E+03 / CH3+OH<=>CH2OH+H 1.204E+10 0.00 1.389E+04 REV/ 6.433E+13 -0.95 9.099E+03 / CH3+OH<=>CH2+H2O 5.600E+07 1.60 5.420E+03 REV/ 1.476E+09 1.19 1.647E+04 / CH3+HO2<=>CH3O+OH 1.500E+13 0.00 0.000E+00 REV/ 9.284E+13 -0.12 2.524E+04 / CH3+HO2<=>CH4+O2 3.610E+12 0.00 0.000E+00 REV/ 6.281E+14 -0.10 5.623E+04 / CH3+O<=>CH2O+H 5.540E+13 0.05 -1.360E+02 REV/ 3.873E+15 -0.15 6.841E+04 / CH3+O2<=>CH3O+O 1.375E+13 0.00 3.052E+04 REV/ 8.506E+14 -0.45 2.479E+03 / CH3+O2<=>CH2O+OH 5.870E+11 0.00 1.424E+04 REV/ 1.175E+11 0.19 6.606E+04 / CH3+O2(+M)<=>CH3O2(+M) 1.006E+08 1.63 0.000E+00 !REV/ 7.282E+13 0.42 3.333E+04 / LOW / 3.8160E+31 -4.8900E+00 3.4320E+03 / TROE / 4.5000E-02 8.8010E+02 2.5000E+09 1.7860E+09 / !TROE FALL-OFF REACTION CH3O2+CH2O<=>CH3O2H+HCO 1.990E+12 0.00 1.166E+04 REV/ 1.323E+14 -0.85 9.259E+03 / CH4+CH3O2<=>CH3+CH3O2H 1.810E+11 0.00 1.848E+04 REV/ 2.233E+12 -0.69 -6.550E+02 / CH3OH+CH3O2<=>CH2OH+CH3O2H 1.810E+12 0.00 1.371E+04 REV/ 2.346E+14 -1.03 2.404E+03 / CH3O2+CH3<=>CH3O+CH3O 9.000E+12 0.00 -1.200E+03 REV/ 3.484E+12 0.18 2.828E+04 / CH3O2+HO2<=>CH3O2H+O2 2.470E+11 0.00 -1.570E+03 REV/ 5.302E+14 -0.79 3.552E+04 / CH3O2+CH3O2<=>CH2O+CH3OH+O2 3.110E+14 -1.61 -1.051E+03 REV/ 0.000E+00 0.00 0.000E+00 / CH3O2+CH3O2<=>O2+CH3O+CH3O 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / CH3O2+H<=>CH3O+OH 9.600E+13 0.00 0.000E+00 REV/ 1.719E+09 1.02 4.078E+04 / CH3O2+O<=>CH3O+O2 3.600E+13 0.00 0.000E+00 REV/ 2.253E+11 0.63 5.752E+04 / CH3O2+OH<=>CH3OH+O2 6.000E+13 0.00 0.000E+00 REV/ 1.536E+13 0.43 5.916E+04 / CH3O2H<=>CH3O+OH 6.310E+14 0.00 4.230E+04 REV/ 2.514E+06 1.88 -2.875E+03 / CH2(S)<=>CH2 1.000E+13 0.00 0.000E+00 REV/ 7.161E+15 -0.89 1.143E+04 / CH2(S)+CH4<=>CH3+CH3 1.600E+13 0.00 -5.700E+02 REV/ 5.067E+12 -0.15 1.316E+04 / CH2(S)+O2<=>CO+OH+H 7.000E+13 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / CH2(S)+H2<=>CH3+H 7.000E+13 0.00 0.000E+00 REV/ 2.023E+16 -0.59 1.527E+04 / CH2(S)+H<=>CH2+H 3.000E+13 0.00 0.000E+00 REV/ 2.148E+16 -0.89 1.143E+04 / CH2(S)+H<=>CH+H2 3.000E+13 0.00 0.000E+00 REV/ 6.945E+13 -0.25 1.248E+04 / CH2(S)+O<=>CO+H+H 3.000E+13 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / CH2(S)+OH<=>CH2O+H 3.000E+13 0.00 0.000E+00 REV/ 1.155E+18 -0.77 8.523E+04 / CH2(S)+CO2<=>CH2O+CO 3.000E+12 0.00 0.000E+00 REV/ 4.366E+10 0.42 5.981E+04 / CH2+H(+M)<=>CH3(+M) 2.500E+16 -0.80 0.000E+00 !REV/ 4.029E+15 -0.23 1.074E+05 / LOW / 3.2000E+27 -3.1400E+00 1.2300E+03 / TROE / 6.8000E-01 7.8000E+01 1.9950E+03 5.5900E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ CH2+O2<=>CO+H2O 7.280E+19 -2.54 1.809E+03 REV/ 1.113E+16 -1.21 1.758E+05 / CH2+O2<=>HCO+OH 1.290E+20 -3.30 2.840E+02 REV/ 6.150E+16 -2.52 7.113E+04 / CH2+O2<=>CO2+H+H 3.290E+21 -3.30 2.868E+03 REV/ 0.000E+00 0.00 0.000E+00 / CH2+O2<=>CH2O+O 3.290E+21 -3.30 2.868E+03 REV/ 5.063E+20 -2.79 5.994E+04 / CH2+O2<=>CO2+H2 1.010E+21 -3.30 1.508E+03 REV/ 3.837E+22 -3.05 1.860E+05 / CH2+O<=>CO+H+H 5.000E+13 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / CH2+H<=>CH+H2 1.000E+18 -1.56 0.000E+00 REV/ 3.233E+15 -0.92 1.050E+03 / DUP CH2+OH<=>CH+H2O 1.130E+07 2.00 3.000E+03 REV/ 3.887E+05 2.53 1.894E+04 / CH+O2<=>HCO+O 3.300E+13 0.00 0.000E+00 REV/ 9.272E+12 0.16 7.121E+04 / C+OH<=>CO+H 5.000E+13 0.00 0.000E+00 REV/ 1.356E+15 0.00 1.543E+05 / C+O2<=>CO+O 5.000E+13 0.00 0.000E+00 REV/ 1.070E+14 0.00 1.382E+05 / CH+H<=>C+H2 5.000E+13 0.00 0.000E+00 REV/ 2.043E+14 0.00 2.382E+04 / CH+O<=>CO+H 5.700E+13 0.00 0.000E+00 REV/ 2.774E+15 0.00 1.760E+05 / CH+OH<=>HCO+H 3.000E+13 0.00 0.000E+00 REV/ 5.069E+14 0.00 8.811E+04 / CH2+H<=>CH+H2 2.700E+11 0.67 2.570E+04 REV/ 1.897E+11 0.67 2.873E+04 / DUP CH+H2O<=>H+CH2O 1.713E+13 0.00 -7.550E+02 REV/ 8.372E+14 0.00 5.752E+04 / CH+CO2<=>HCO+CO 1.700E+12 0.00 6.850E+02 REV/ 2.565E+11 0.00 6.646E+04 / C2H6(+M)<=>CH3+CH3(+M) 1.880E+50 -9.72 1.073E+05 !REV/ 9.096E+41 -8.29 1.630E+04 / LOW / 3.7200E+65 -1.3140E+01 1.0158E+05 / TROE / 3.9000E-01 1.0000E+02 1.9000E+03 6.0000E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ C2H5+H(+M)<=>C2H6(+M) 5.270E+17 -0.99 1.580E+03 !REV/ 2.279E+21 -1.40 1.029E+05 / LOW / 1.9900E+41 -7.0800E+00 6.6850E+03 / TROE / 8.4200E-01 1.2500E+02 2.2190E+03 6.8820E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ C2H6+H<=>C2H5+H2 5.740E+07 1.96 7.190E+03 REV/ 5.300E+03 2.64 9.420E+03 / C2H6+O<=>C2H5+OH 3.550E+06 2.40 5.830E+03 REV/ 1.721E+02 3.06 6.648E+03 / C2H6+OH<=>C2H5+H2O 1.480E+07 1.90 9.500E+02 REV/ 1.454E+04 2.48 1.807E+04 / C2H6+O2<=>C2H5+HO2 6.030E+13 0.00 5.187E+04 REV/ 2.921E+10 0.33 -5.930E+02 / C2H6+CH3<=>C2H5+CH4 1.510E-07 6.00 6.047E+03 REV/ 1.273E-08 6.24 9.817E+03 / C2H6+HO2<=>C2H5+H2O2 1.904E+12 0.00 1.589E+04 REV/ 1.018E+11 -0.01 2.119E+03 / C2H6+CH3O2<=>C2H5+CH3O2H 1.320E+13 0.00 2.047E+04 REV/ 1.373E+13 -0.46 5.104E+03 / C2H6+CH3O<=>C2H5+CH3OH 2.410E+11 0.00 7.090E+03 REV/ 4.779E+08 0.47 9.547E+03 / C2H6+CH<=>C2H5+CH2 1.100E+14 0.00 -2.600E+02 REV/ 3.142E+12 0.04 9.200E+02 / CH2(S)+C2H6<=>CH3+C2H5 1.200E+14 0.00 0.000E+00 REV/ 3.203E+12 0.09 1.750E+04 / C2H4+H(+M)<=>C2H5(+M) 3.975E+09 1.28 1.292E+03 !REV/ 7.153E+09 1.16 3.678E+04 / LOW / 2.7910E+18 0.0000E+00 7.5500E+02 / TROE / 7.6000E-01 4.0000E+01 1.0250E+03 1.0000+100 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ H2+CH3O2<=>H+CH3O2H 1.500E+14 0.00 2.603E+04 REV/ 1.689E+18 -1.14 8.434E+03 / H2+C2H5O2<=>H+C2H5O2H 1.500E+14 0.00 2.603E+04 REV/ 1.692E+18 -1.14 8.438E+03 / C2H5+O2<=>C2H5O+O 1.100E-17 -0.21 2.794E+04 REV/ 9.675E-14 -1.26 2.313E+03 / C2H5+C2H3<=>C2H4+C2H4 6.859E+11 0.11 -4.300E+03 REV/ 4.820E+14 0.00 7.153E+04 / CH3+C2H5<=>CH4+C2H4 1.950E+13 -0.50 0.000E+00 REV/ 3.949E+15 -0.55 6.961E+04 / C2H5+H<=>CH3+CH3 1.510E+18 -1.03 4.380E+03 REV/ 3.160E+13 0.00 1.467E+04 / C2H5+H<=>C2H4+H2 2.000E+12 0.00 0.000E+00 REV/ 4.438E+11 0.40 6.807E+04 / C2H5+O<=>CH3CHO+H 1.100E+14 0.00 0.000E+00 REV/ 1.045E+17 -0.50 7.742E+04 / C2H5+HO2<=>C2H5O+OH 1.100E+13 0.00 0.000E+00 REV/ 9.680E+15 -0.72 2.765E+04 / CH3O2+C2H5<=>CH3O+C2H5O 8.000E+12 0.00 -1.000E+03 REV/ 4.404E+14 -0.42 3.089E+04 / C2H5O+O2<=>CH3CHO+HO2 4.280E+10 0.00 1.097E+03 REV/ 1.322E+08 0.61 3.414E+04 / C2H5O<=>CH3+CH2O 1.321E+20 -2.02 2.075E+04 REV/ 3.000E+11 0.00 6.336E+03 / C2H5O<=>CH3CHO+H 5.425E+15 -0.69 2.223E+04 REV/ 8.000E+12 0.00 6.400E+03 / C2H5O2<=>C2H5+O2 1.341E+19 -1.40 3.456E+04 REV/ 2.940E+13 -0.44 0.000E+00 / C2H5O2+CH2O<=>C2H5O2H+HCO 1.990E+12 0.00 1.166E+04 REV/ 1.325E+14 -0.85 9.263E+03 / CH4+C2H5O2<=>CH3+C2H5O2H 1.810E+11 0.00 1.848E+04 REV/ 2.237E+12 -0.69 -6.510E+02 / CH3OH+C2H5O2<=>CH2OH+C2H5O2H 1.810E+12 0.00 1.371E+04 REV/ 2.350E+14 -1.03 2.408E+03 / C2H5O2+HO2<=>C2H5O2H+O2 1.750E+10 0.00 -3.275E+03 REV/ 3.763E+13 -0.79 3.382E+04 / C2H6+C2H5O2<=>C2H5+C2H5O2H 1.320E+13 0.00 2.047E+04 REV/ 1.375E+13 -0.46 5.108E+03 / C2H5O2H<=>C2H5O+OH 6.310E+14 0.00 4.230E+04 REV/ 5.661E+08 1.03 -1.705E+03 / C2H5O2<=>C2H4O2H 7.900E+06 1.79 3.582E+04 REV/ 1.170E+07 1.04 1.798E+04 / C2H5O2<=>C2H4+HO2 8.800E+05 2.24 2.961E+04 REV/ 2.246E+00 3.25 8.429E+03 / C2H4O2H<=>C2H4O1-2+OH 1.320E+10 0.72 1.538E+04 REV/ 1.223E+10 1.02 3.265E+04 / C2H4O2H<=>C2H4+HO2 1.280E+11 0.52 1.615E+04 REV/ 6.180E+08 1.18 1.311E+04 / C2H5O2<=>C2H5O+O 2.980E+15 -0.09 6.160E+04 REV/ 5.746E+13 -0.18 1.411E+03 / C2H4O1-2<=>CH3+HCO 3.630E+13 0.00 5.720E+04 REV/ 1.006E+04 1.55 -2.750E+03 / C2H4O1-2<=>CH3CHO 7.407E+12 0.00 5.380E+04 REV/ 9.013E+10 0.21 8.080E+04 / C2H4O1-2+OH<=>C2H3O1-2+H2O 1.780E+13 0.00 3.610E+03 REV/ 1.351E+10 0.69 2.474E+04 / C2H4O1-2+H<=>C2H3O1-2+H2 8.000E+13 0.00 9.680E+03 REV/ 5.707E+09 0.80 1.592E+04 / C2H4O1-2+HO2<=>C2H3O1-2+H2O2 1.130E+13 0.00 3.043E+04 REV/ 4.666E+11 0.10 2.067E+04 / C2H4O1-2+CH3O2<=>C2H3O1-2+CH3O2H 1.130E+13 0.00 3.043E+04 REV/ 9.078E+12 -0.34 1.907E+04 / C2H4O1-2+C2H5O2<=>C2H3O1-2+C2H5O2H 1.130E+13 0.00 3.043E+04 REV/ 9.093E+12 -0.34 1.908E+04 / C2H4O1-2+CH3<=>C2H3O1-2+CH4 1.070E+12 0.00 1.183E+04 REV/ 6.967E+10 0.35 1.961E+04 / C2H4O1-2+CH3O<=>C2H3O1-2+CH3OH 1.200E+11 0.00 6.750E+03 REV/ 1.839E+08 0.59 1.322E+04 / C2H3O1-2<=>CH3CO 8.500E+14 0.00 1.400E+04 REV/ 1.002E+14 0.04 4.871E+04 / C2H3O1-2<=>CH2CHO 1.000E+14 0.00 1.400E+04 REV/ 1.245E+15 -0.38 4.401E+04 / CH3CHO<=>CH3+HCO 7.687E+20 -1.34 8.695E+04 REV/ 1.750E+13 0.00 0.000E+00 / CH3CHO+H<=>CH3CO+H2 1.110E+13 0.00 3.110E+03 REV/ 7.674E+09 0.63 1.706E+04 / CH3CHO+O<=>CH3CO+OH 5.940E+12 0.00 1.868E+03 REV/ 2.156E+09 0.61 1.441E+04 / CH3CHO+OH<=>CH3CO+H2O 2.000E+06 1.80 1.300E+03 REV/ 1.471E+04 2.33 3.014E+04 / CH3CHO+O2<=>CH3CO+HO2 3.010E+13 0.00 3.915E+04 REV/ 1.092E+11 0.28 -1.588E+03 / CH3CHO+CH3<=>CH3CO+CH4 1.760E+03 2.79 4.950E+03 REV/ 1.111E+03 2.98 2.044E+04 / CH3CHO+HO2<=>CH3CO+H2O2 3.010E+12 0.00 1.192E+04 REV/ 1.205E+12 -0.06 9.877E+03 / CH3O2+CH3CHO<=>CH3O2H+CH3CO 3.010E+12 0.00 1.192E+04 REV/ 2.344E+13 -0.51 8.282E+03 / CH3CHO+CH3CO3<=>CH3CO+CH3CO3H 3.010E+12 0.00 1.192E+04 REV/ 1.922E+12 -0.01 1.265E+04 / CH3CHO+OH<=>CH3+HOCHO 3.000E+15 -1.08 0.000E+00 REV/ 2.371E+16 -1.28 2.375E+04 / CH3CHO+OH<=>CH2CHO+H2O 1.720E+05 2.40 8.150E+02 REV/ 1.336E+05 2.51 2.495E+04 / CH3CO(+M)<=>CH3+CO(+M) 3.000E+12 0.00 1.672E+04 !REV/ 2.976E+06 1.37 4.049E+03 / LOW / 1.2000E+15 0.0000E+00 1.2518E+04 / !LINDEMANN FALL-OFF REACTION CH3CO+H<=>CH2CO+H2 2.000E+13 0.00 0.000E+00 REV/ 3.841E+15 -0.55 6.073E+04 / CH3CO+O<=>CH2CO+OH 2.000E+13 0.00 0.000E+00 REV/ 2.016E+15 -0.57 5.932E+04 / CH3CO+CH3<=>CH2CO+CH4 5.000E+13 0.00 0.000E+00 REV/ 8.766E+18 -0.99 6.227E+04 / CH3CO3<=>CH3CO+O2 6.863E+19 -1.95 3.853E+04 REV/ 1.200E+11 0.00 -1.100E+03 / CH3CO3+HO2<=>CH3CO3H+O2 1.750E+10 0.00 -3.275E+03 REV/ 3.080E+12 -0.29 3.818E+04 / H2O2+CH3CO3<=>HO2+CH3CO3H 2.410E+12 0.00 9.936E+03 REV/ 3.845E+12 0.05 1.271E+04 / CH4+CH3CO3<=>CH3+CH3CO3H 1.810E+11 0.00 1.848E+04 REV/ 1.831E+11 -0.20 3.711E+03 / CH2O+CH3CO3<=>HCO+CH3CO3H 1.990E+12 0.00 1.166E+04 REV/ 1.085E+13 -0.36 1.362E+04 / C2H6+CH3CO3<=>C2H5+CH3CO3H 1.700E+13 0.00 2.046E+04 REV/ 1.450E+12 0.04 9.460E+03 / CH3CO3H<=>CH3CO2+OH 5.010E+14 0.00 4.015E+04 REV/ 3.618E+07 1.76 1.338E+03 / CH3CO2+M<=>CH3+CO2+M 4.400E+15 0.00 1.050E+04 REV/ 4.548E+08 1.38 1.752E+04 / CH2CHO<=>CH2CO+H 1.098E+13 0.41 5.043E+04 REV/ 5.000E+13 0.00 1.230E+04 / CH2CHO+O2<=>CH2O+CO+OH 2.000E+13 0.00 4.200E+03 REV/ 0.000E+00 0.00 0.000E+00 / CH2+CO(+M)<=>CH2CO(+M) 8.100E+11 0.00 0.000E+00 !REV/ 6.331E+19 -1.61 7.724E+04 / LOW / 2.6900E+33 -5.1100E+00 7.0950E+03 / TROE / 5.9070E-01 2.7500E+02 1.2260E+03 5.1850E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ CH2CO+H<=>CH3+CO 1.100E+13 0.00 3.400E+03 REV/ 2.400E+12 0.00 4.020E+04 / CH2CO+H<=>HCCO+H2 2.000E+14 0.00 8.000E+03 REV/ 3.001E+09 0.64 -1.100E+03 / CH2CO+O<=>CH2+CO2 1.750E+12 0.00 1.350E+03 REV/ 1.241E+10 0.68 5.168E+04 / CH2CO+O<=>HCCO+OH 1.000E+13 0.00 8.000E+03 REV/ 7.877E+07 0.62 -2.512E+03 / CH2CO+OH<=>HCCO+H2O 1.000E+13 0.00 2.000E+03 REV/ 1.597E+09 0.53 7.792E+03 / CH2CO+OH<=>CH2OH+CO 3.730E+12 0.00 -1.013E+03 REV/ 4.110E+07 1.24 2.436E+04 / CH2(S)+CH2CO<=>C2H4+CO 1.600E+14 0.00 0.000E+00 REV/ 1.011E+12 0.96 1.032E+05 / HCCO+OH<=>HCO+HCO 1.000E+13 0.00 0.000E+00 REV/ 4.820E+13 0.00 4.036E+04 / H+HCCO<=>CH2(S)+CO 1.100E+13 0.00 0.000E+00 REV/ 5.229E+06 2.14 2.399E+04 / HCCO+O<=>H+CO+CO 8.000E+13 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / HCCO+O2<=>CO2+HCO 2.400E+11 0.00 -8.540E+02 REV/ 1.030E+11 0.84 1.308E+05 / HCCO+M<=>CH+CO+M 6.500E+15 0.00 5.882E+04 REV/ 1.792E+10 1.61 -8.270E+03 / CH+CH2O<=>H+CH2CO 9.460E+13 0.00 -5.150E+02 REV/ 1.623E+15 0.00 6.906E+04 / CH+HCCO<=>CO+C2H2 5.000E+13 0.00 0.000E+00 REV/ 1.721E+17 0.00 1.646E+05 / C2H3+H(+M)<=>C2H4(+M) 1.360E+14 0.17 6.600E+02 !REV/ 1.720E+17 -0.06 1.120E+05 / LOW / 1.4000E+30 -3.8600E+00 3.3200E+03 / TROE / 7.8200E-01 2.0750E+02 2.6630E+03 6.0950E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ C2H4(+M)<=>C2H2+H2(+M) 8.000E+12 0.44 8.877E+04 !REV/ 6.183E+09 0.92 4.669E+04 / LOW / 1.5800E+51 -9.3000E+00 9.7800E+04 / TROE / 7.3500E-01 1.8000E+02 1.0350E+03 5.4170E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ C2H4+H<=>C2H3+H2 5.070E+07 1.93 1.295E+04 REV/ 1.601E+04 2.44 5.190E+03 / C2H4+O<=>CH3+HCO 8.564E+06 1.88 1.830E+02 REV/ 3.333E+02 2.60 2.614E+04 / C2H4+O<=>CH2CHO+H 4.986E+06 1.88 1.830E+02 REV/ 1.558E+09 1.20 1.878E+04 / C2H4+OH<=>C2H3+H2O 2.090E+06 2.01 1.160E+03 REV/ 7.021E+03 2.41 8.292E+03 / C2H4+CH3<=>C2H3+CH4 6.620E+00 3.70 9.500E+03 REV/ 1.440E+00 4.02 5.472E+03 / C2H4+O2<=>C2H3+HO2 4.000E+13 0.00 5.820E+04 REV/ 6.626E+10 0.16 -4.249E+03 / C2H4+CH3O<=>C2H3+CH3OH 1.200E+11 0.00 6.750E+03 REV/ 8.138E+08 0.29 -7.830E+02 / C2H4+CH3O2<=>C2H3+CH3O2H 2.230E+12 0.00 1.719E+04 REV/ 7.929E+12 -0.63 -8.167E+03 / C2H4+C2H5O2<=>C2H3+C2H5O2H 2.230E+12 0.00 1.719E+04 REV/ 7.943E+12 -0.63 -8.163E+03 / C2H4+CH3CO3<=>C2H3+CH3CO3H 1.130E+13 0.00 3.043E+04 REV/ 3.295E+12 -0.14 9.440E+03 / C2H4+CH3O2<=>C2H4O1-2+CH3O 2.820E+12 0.00 1.711E+04 REV/ 3.385E+13 -0.07 4.166E+04 / C2H4+C2H5O2<=>C2H4O1-2+C2H5O 2.820E+12 0.00 1.711E+04 REV/ 7.638E+15 -0.92 4.283E+04 / C2H4+HO2<=>C2H4O1-2+OH 2.230E+12 0.00 1.719E+04 REV/ 4.280E+14 -0.36 3.750E+04 / CH+CH4<=>C2H4+H 6.000E+13 0.00 0.000E+00 REV/ 3.573E+14 0.00 5.548E+04 / CH2(S)+CH3<=>C2H4+H 2.000E+13 0.00 0.000E+00 REV/ 6.131E+19 -1.22 7.305E+04 / C2H2+H(+M)<=>C2H3(+M) 5.600E+12 0.00 2.400E+03 !REV/ 2.288E+12 0.02 3.672E+04 / LOW / 3.8000E+40 -7.2700E+00 7.2200E+03 / TROE / 7.5100E-01 9.8500E+01 1.3020E+03 4.1670E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ C2H3+O2<=>C2H2+HO2 2.120E-06 6.00 9.484E+03 REV/ 1.087E-05 5.91 2.404E+04 / C2H3+O2<=>CH2O+HCO 1.700E+29 -5.31 6.500E+03 REV/ 7.987E+27 -4.88 9.345E+04 / C2H3+O2<=>CH2CHO+O 5.500E+14 -0.61 5.260E+03 REV/ 2.968E+18 -1.38 1.630E+04 / CH3+C2H3<=>CH4+C2H2 3.920E+11 0.00 0.000E+00 REV/ 3.497E+14 -0.19 7.078E+04 / C2H3+H<=>C2H2+H2 3.000E+13 0.00 0.000E+00 REV/ 2.932E+13 0.25 6.924E+04 / C2H3+OH<=>C2H2+H2O 5.000E+12 0.00 0.000E+00 REV/ 5.200E+13 0.15 8.413E+04 / C2H+H(+M)<=>C2H2(+M) 1.000E+17 0.00 0.000E+00 !REV/ 3.155E+20 -0.54 1.329E+05 / LOW / 3.7500E+33 -4.8000E+00 1.9000E+03 / TROE / 6.4600E-01 1.3200E+02 1.3150E+03 5.5660E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ C2H2+O2<=>HCCO+OH 2.000E+08 1.50 3.010E+04 REV/ 1.582E+07 0.96 2.682E+04 / O+C2H2<=>C2H+OH 4.600E+19 -1.40 2.895E+04 REV/ 3.056E+15 -0.60 -1.782E+03 / C2H2+O<=>CH2+CO 6.940E+06 2.00 1.900E+03 REV/ 6.531E+04 2.32 5.077E+04 / C2H2+O<=>HCCO+H 1.350E+07 2.00 1.900E+03 REV/ 3.732E+08 1.07 1.535E+04 / C2H2+OH<=>C2H+H2O 3.370E+07 2.00 1.400E+04 REV/ 4.538E+04 2.71 -4.280E+02 / C2H2+OH<=>CH2CO+H 3.236E+13 0.00 1.200E+04 REV/ 1.136E+20 -1.55 3.596E+04 / C2H2+OH<=>CH3+CO 4.830E-04 4.00 -2.000E+03 REV/ 3.495E-06 4.64 5.212E+04 / OH+C2H2<=>H+HCCOH 5.040E+05 2.30 1.350E+04 REV/ 1.902E+11 1.04 6.352E+03 / H+HCCOH<=>H+CH2CO 1.000E+13 0.00 0.000E+00 REV/ 9.299E+13 -0.29 3.111E+04 / C2H5OH(+M)<=>CH2OH+CH3(+M) 5.710E+23 -1.68 9.440E+04 !REV/ 2.393E+15 -0.22 5.023E+03 / LOW / 3.1100E+85 -1.8840E+01 1.1310E+05 / TROE / 5.0000E-01 5.5000E+02 8.2500E+02 6.1000E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/5/ CO/2/ CO2/3/ C2H5OH(+M)<=>C2H5+OH(+M) 2.400E+23 -1.62 9.954E+04 !REV/ 8.998E+15 -0.24 4.653E+03 / LOW / 5.1100E+85 -1.8800E+01 1.1877E+05 / TROE / 5.0000E-01 6.5000E+02 8.0000E+02 1.0000E+15 / !TROE FALL-OFF REACTION H2/2/ H2O/5/ CO/2/ CO2/3/ C2H5OH(+M)<=>C2H4+H2O(+M) 2.790E+13 0.09 6.614E+04 !REV/ 2.470E+06 1.76 5.422E+04 / LOW / 2.5700E+83 -1.8850E+01 8.6453E+04 / TROE / 7.0000E-01 3.5000E+02 8.0000E+02 3.8000E+03 / !TROE FALL-OFF REACTION H2O/5/ C2H5OH(+M)<=>CH3CHO+H2(+M) 7.240E+11 0.10 9.101E+04 !REV/ 4.912E+07 0.99 7.496E+04 / LOW / 4.4600E+87 -1.9420E+01 1.1558E+05 / TROE / 9.0000E-01 9.0000E+02 1.1000E+03 3.5000E+03 / !TROE FALL-OFF REACTION H2O/5/ C2H5OH+O2<=>PC2H4OH+HO2 2.000E+13 0.00 5.280E+04 REV/ 2.192E+10 0.28 4.430E+02 / C2H5OH+O2<=>SC2H4OH+HO2 1.500E+13 0.00 5.015E+04 REV/ 1.946E+11 0.09 4.879E+03 / C2H5OH+OH<=>PC2H4OH+H2O 1.740E+11 0.27 6.000E+02 REV/ 3.869E+08 0.79 1.783E+04 / C2H5OH+OH<=>SC2H4OH+H2O 4.640E+11 0.15 0.000E+00 REV/ 1.221E+10 0.48 2.431E+04 / C2H5OH+OH<=>C2H5O+H2O 7.460E+11 0.30 1.634E+03 REV/ 3.652E+11 0.41 1.631E+04 / C2H5OH+H<=>PC2H4OH+H2 1.230E+07 1.80 5.098E+03 REV/ 2.570E+03 2.43 7.432E+03 / C2H5OH+H<=>SC2H4OH+H2 2.580E+07 1.65 2.827E+03 REV/ 6.380E+04 2.09 1.225E+04 / C2H5OH+H<=>C2H5O+H2 1.500E+07 1.60 3.038E+03 REV/ 6.901E+05 1.81 2.821E+03 / C2H5OH+HO2<=>PC2H4OH+H2O2 1.230E+04 2.55 1.575E+04 REV/ 1.488E+03 2.48 2.083E+03 / C2H5OH+HO2<=>SC2H4OH+H2O2 8.200E+03 2.55 1.075E+04 REV/ 1.174E+04 2.29 4.169E+03 / C2H5OH+HO2<=>C2H5O+H2O2 2.500E+12 0.00 2.400E+04 REV/ 6.658E+13 -0.48 7.782E+03 / C2H5OH+CH3O2<=>PC2H4OH+CH3O2H 1.230E+04 2.55 1.575E+04 REV/ 2.894E+04 2.04 4.880E+02 / C2H5OH+CH3O2<=>SC2H4OH+CH3O2H 8.200E+03 2.55 1.075E+04 REV/ 2.284E+05 1.85 2.574E+03 / C2H5OH+CH3O2<=>C2H5O+CH3O2H 2.500E+12 0.00 2.400E+04 REV/ 1.295E+15 -0.93 6.187E+03 / C2H5OH+O<=>PC2H4OH+OH 9.410E+07 1.70 5.459E+03 REV/ 1.032E+04 2.31 6.381E+03 / C2H5OH+O<=>SC2H4OH+OH 1.880E+07 1.85 1.824E+03 REV/ 2.440E+04 2.27 9.832E+03 / C2H5OH+O<=>C2H5O+OH 1.580E+07 2.00 4.448E+03 REV/ 3.815E+05 2.19 2.819E+03 / C2H5OH+CH3<=>PC2H4OH+CH4 1.330E+02 3.18 9.362E+03 REV/ 2.537E+01 3.36 1.324E+04 / C2H5OH+CH3<=>SC2H4OH+CH4 4.440E+02 2.90 7.690E+03 REV/ 1.002E+03 2.89 1.865E+04 / C2H5OH+CH3<=>C2H5O+CH4 1.340E+02 2.92 7.452E+03 REV/ 5.627E+03 2.69 8.775E+03 / C2H5OH+C2H5<=>PC2H4OH+C2H6 5.000E+10 0.00 1.340E+04 REV/ 6.995E+10 0.00 2.699E+04 / C2H5OH+C2H5<=>SC2H4OH+C2H6 5.000E+10 0.00 1.040E+04 REV/ 6.995E+10 0.00 2.399E+00 / PC2H4OH<=>C2H4+OH 1.047E+25 -3.99 3.039E+04 REV/ 4.170E+20 -2.84 1.240E+03 / SC2H4OH+M<=>CH3CHO+H+M 1.000E+14 0.00 2.500E+04 REV/ 2.744E+12 0.46 -4.700E+02 / O2C2H4OH<=>PC2H4OH+O2 3.900E+16 -1.00 3.000E+04 REV/ 1.200E+11 0.00 -1.100E+03 / O2C2H4OH<=>OH+CH2O+CH2O 3.125E+09 0.00 1.890E+04 REV/ 0.000E+00 0.00 0.000E+00 / SC2H4OH+O2<=>CH3CHO+HO2 3.810E+06 2.00 1.641E+03 REV/ 2.190E+05 2.39 2.504E+04 / CH3COCH3(+M)<=>CH3CO+CH3(+M) 7.108E+21 -1.57 8.468E+04 !REV/ 1.000E+13 0.00 3.000E+00 / LOW / 9.9150E+89 -2.0380E+01 1.0735E+05 / TROE / 2.8400E-01 1.9700E+01 1.0000E+10 9.9240E+09 / !TROE FALL-OFF REACTION CH3COCH3+OH<=>CH3COCH2+H2O 1.958E+01 3.64 -1.128E+03 REV/ 1.354E+01 3.47 2.313E+04 / CH3COCH3+H<=>CH3COCH2+H2 2.940E+06 2.43 5.160E+03 REV/ 1.911E+05 2.37 1.453E+04 / CH3COCH3+O<=>CH3COCH2+OH 5.130E+11 0.21 4.890E+03 REV/ 1.751E+10 0.14 1.285E+04 / CH3COCH3+CH3<=>CH3COCH2+CH4 3.960E+11 0.00 9.784E+03 REV/ 2.350E+13 -0.50 2.069E+04 / CH3COCH3+CH3O<=>CH3COCH2+CH3OH 4.340E+11 0.00 6.460E+03 REV/ 6.060E+11 -0.27 1.606E+04 / CH3COCH3+O2<=>CH3COCH2+HO2 6.030E+13 0.00 4.850E+04 REV/ 2.057E+13 -0.40 3.181E+03 / CH3COCH3+HO2<=>CH3COCH2+H2O2 1.700E+13 0.00 2.046E+04 REV/ 6.397E+14 -0.75 1.383E+04 / CH3COCH3+CH3O2<=>CH3COCH2+CH3O2H 1.700E+13 0.00 2.046E+04 REV/ 1.245E+16 -1.19 1.223E+04 / CH3COCH2<=>CH2CO+CH3 1.000E+14 0.00 3.100E+04 REV/ 1.000E+11 0.00 6.000E+03 / CH3COCH2O2<=>CH3COCH2+O2 2.021E+15 -0.96 2.446E+04 REV/ 1.200E+11 0.00 -1.100E+03 / CH3COCH3+CH3COCH2O2<=>CH3COCH2+CH3COCH2O2H 1.000E+11 0.00 5.000E+03 REV/ 1.995E+10 0.00 1.000E+04 / CH2O+CH3COCH2O2<=>HCO+CH3COCH2O2H 1.288E+11 0.00 9.000E+03 REV/ 2.512E+10 0.00 1.010E+04 / HO2+CH3COCH2O2<=>CH3COCH2O2H+O2 1.000E+12 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / CH3COCH2O2H<=>CH3COCH2O+OH 1.000E+16 0.00 4.300E+04 REV/ 4.242E+08 1.74 -4.342E+03 / CH3COCH2O<=>CH3CO+CH2O 3.732E+20 -2.18 1.726E+04 REV/ 1.000E+11 0.00 1.190E+04 / C2H3CHO<=>C2H3+HCO 2.003E+24 -2.14 1.034E+05 REV/ 1.810E+13 0.00 0.000E+00 / C2H3CHO+H<=>C2H3CO+H2 1.340E+13 0.00 3.300E+03 REV/ 3.309E+10 0.61 2.268E+04 / C2H3CHO+O<=>C2H3CO+OH 5.940E+12 0.00 1.868E+03 REV/ 7.700E+09 0.59 1.984E+04 / C2H3CHO+OH<=>C2H3CO+H2O 9.240E+06 1.50 -9.620E+02 REV/ 2.428E+05 2.01 3.331E+04 / C2H3CHO+O2<=>C2H3CO+HO2 1.005E+13 0.00 4.070E+04 REV/ 1.302E+11 0.27 5.391E+03 / C2H3CHO+HO2<=>C2H3CO+H2O2 3.010E+12 0.00 1.192E+04 REV/ 4.303E+12 -0.08 1.530E+04 / C2H3CHO+CH3<=>C2H3CO+CH4 2.608E+06 1.78 5.911E+03 REV/ 5.878E+06 1.95 2.683E+04 / C2H3CHO+C2H3<=>C2H3CO+C2H4 1.740E+12 0.00 8.440E+03 REV/ 1.000E+13 0.00 2.800E+04 / C2H3CHO+CH3O<=>C2H3CO+CH3OH 1.000E+12 0.00 3.300E+03 REV/ 5.304E+10 0.40 2.291E+04 / C2H3CHO+CH3O2<=>C2H3CO+CH3O2H 3.010E+12 0.00 1.192E+04 REV/ 8.371E+13 -0.53 1.371E+04 / C2H3CO<=>C2H3+CO 1.370E+21 -2.18 3.941E+04 REV/ 1.510E+11 0.00 4.810E+03 / C2H5CHO<=>C2H5+HCO 1.500E+27 -3.21 8.704E+04 REV/ 1.810E+13 0.00 0.000E+00 / C2H5CHO+H<=>C2H5CO+H2 4.000E+13 0.00 4.200E+03 REV/ 2.371E+10 0.65 1.813E+04 / C2H5CHO+O<=>C2H5CO+OH 5.000E+12 0.00 1.790E+03 REV/ 1.556E+09 0.63 1.431E+04 / C2H5CHO+OH<=>C2H5CO+H2O 2.690E+10 0.76 -3.400E+02 REV/ 1.697E+08 1.31 2.848E+04 / C2H5CHO+CH3<=>C2H5CO+CH4 2.608E+06 1.78 5.911E+03 REV/ 1.411E+06 1.99 2.138E+04 / C2H5CHO+HO2<=>C2H5CO+H2O2 2.800E+12 0.00 1.360E+04 REV/ 9.607E+11 -0.04 1.153E+04 / C2H5CHO+CH3O<=>C2H5CO+CH3OH 1.000E+12 0.00 3.300E+03 REV/ 1.273E+10 0.44 1.746E+04 / C2H5CHO+CH3O2<=>C2H5CO+CH3O2H 3.010E+12 0.00 1.192E+04 REV/ 2.009E+13 -0.49 8.260E+03 / C2H5CHO+C2H5<=>C2H5CO+C2H6 1.000E+12 0.00 8.000E+03 REV/ 6.420E+12 -0.03 1.970E+04 / C2H5CHO+C2H5O<=>C2H5CO+C2H5OH 6.026E+11 0.00 3.300E+03 REV/ 3.020E+11 0.00 1.816E+04 / C2H5CHO+C2H5O2<=>C2H5CO+C2H5O2H 3.010E+12 0.00 1.192E+04 REV/ 2.013E+13 -0.49 8.264E+03 / C2H5CHO+O2<=>C2H5CO+HO2 1.005E+13 0.00 4.070E+04 REV/ 3.125E+10 0.31 -5.800E+01 / C2H5CHO+CH3CO3<=>C2H5CO+CH3CO3H 3.010E+12 0.00 1.192E+04 REV/ 1.648E+12 0.01 1.263E+04 / C2H5CHO+C2H3<=>C2H5CO+C2H4 1.700E+12 0.00 8.440E+03 REV/ 3.191E+12 0.15 3.013E+04 / C2H5CO<=>C2H5+CO 2.463E+23 -3.21 1.755E+04 REV/ 1.510E+11 0.00 4.810E+03 / CH3OCH3(+M)<=>CH3+CH3O(+M) 4.061E+15 0.16 7.949E+04 !REV/ 1.254E+07 1.72 -3.637E+03 / LOW / 2.5410E+70 -1.4430E+01 9.6080E+04 / TROE / 8.3300E-01 4.7060E+09 5.7944E+02 6.7000E+08 / !TROE FALL-OFF REACTION CH3OCH3+OH<=>CH3OCH2+H2O 6.324E+06 2.00 -6.517E+02 REV/ 7.877E+04 2.24 2.121E+04 / CH3OCH3+H<=>CH3OCH2+H2 7.721E+06 2.09 3.384E+03 REV/ 9.038E+03 2.43 1.036E+04 / CH3OCH3+O<=>CH3OCH2+OH 1.855E-03 5.29 -1.090E+02 REV/ 1.140E-06 5.61 5.451E+03 / CH3OCH3+HO2<=>CH3OCH2+H2O2 1.680E+13 0.00 1.769E+04 REV/ 1.138E+13 -0.35 8.657E+03 / CH3OCH3+CH3O2<=>CH3OCH2+CH3O2H 1.680E+13 0.00 1.769E+04 REV/ 2.215E+14 -0.80 7.062E+03 / CH3OCH3+CH3<=>CH3OCH2+CH4 1.445E-06 5.73 5.699E+03 REV/ 1.544E-06 5.63 1.421E+04 / CH3OCH3+O2<=>CH3OCH2+HO2 4.100E+13 0.00 4.491E+04 REV/ 2.518E+11 -0.01 -2.806E+03 / CH3OCH3+CH3O<=>CH3OCH2+CH3OH 6.020E+11 0.00 4.074E+03 REV/ 7.383E+10 -0.27 1.026E+04 / CH3OCH3+CH3OCH2O2<=>CH3OCH2+CH3OCH2O2H 5.000E+12 0.00 1.769E+04 REV/ 6.428E+13 -0.79 7.258E+03 / CH3OCH3+O2CHO<=>CH3OCH2+HO2CHO 4.425E+04 2.60 1.391E+04 REV/ 1.651E-05 4.61 1.172E+03 / CH3OCH3+OCHO<=>CH3OCH2+HOCHO 1.000E+13 0.00 1.769E+04 REV/ 7.195E+12 -0.31 3.313E+04 / CH3OCH2<=>CH2O+CH3 1.600E+13 0.00 2.550E+04 REV/ 2.601E+05 1.88 1.667E+04 / CH3OCH2+CH3O<=>CH3OCH3+CH2O 2.410E+13 0.00 0.000E+00 REV/ 1.250E+14 0.32 7.854E+04 / CH3OCH2+CH2O<=>CH3OCH3+HCO 5.490E+03 2.80 5.862E+03 REV/ 2.768E+04 2.74 1.408E+04 / CH3OCH2+CH3CHO<=>CH3OCH3+CH3CO 1.260E+12 0.00 8.499E+03 REV/ 7.746E+11 0.28 1.698E+04 / CH3OCH2O2<=>CH3OCH2+O2 4.439E+19 -1.59 3.624E+04 REV/ 2.000E+12 0.00 0.000E+00 / CH3OCH2O2+CH2O<=>CH3OCH2O2H+HCO 1.000E+12 0.00 1.166E+04 REV/ 6.482E+13 -0.85 9.455E+03 / CH3OCH2O2+CH3CHO<=>CH3OCH2O2H+CH3CO 2.800E+12 0.00 1.360E+04 REV/ 1.000E+12 0.00 1.000E+04 / CH3OCH2O2+CH3OCH2O2<=>O2+CH3OCH2O+CH3OCH2O 2.210E+23 -4.50 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / CH3OCH2O2H<=>CH3OCH2O+OH 2.106E+22 -2.12 4.383E+04 REV/ 2.000E+13 0.00 0.000E+00 / CH3OCH2O<=>CH3O+CH2O 4.384E+19 -2.01 2.519E+04 REV/ 1.000E+11 0.00 1.190E+04 / CH3OCH2O+O2<=>CH3OCHO+HO2 5.000E+10 0.00 5.000E+02 REV/ 1.086E+10 -0.02 4.648E+04 / CH3OCH2O<=>CH3OCHO+H 3.143E+14 -0.48 9.048E+03 REV/ 1.000E+13 0.00 7.838E+03 / CH3OCH2O2<=>CH2OCH2O2H 6.000E+10 0.00 2.158E+04 REV/ 1.248E+12 -0.77 1.112E+04 / CH2OCH2O2H<=>OH+CH2O+CH2O 1.500E+13 0.00 2.076E+04 REV/ 0.000E+00 0.00 0.000E+00 / O2CH2OCH2O2H<=>CH2OCH2O2H+O2 1.924E+19 -1.62 3.627E+04 REV/ 7.000E+11 0.00 0.000E+00 / O2CH2OCH2O2H<=>HO2CH2OCHO+OH 4.000E+10 0.00 1.858E+04 REV/ 1.626E+03 1.68 5.884E+04 / HO2CH2OCHO<=>OCH2OCHO+OH 2.000E+16 0.00 4.050E+04 REV/ 3.666E+08 1.67 -3.152E+03 / OCH2OCHO<=>CH2O+OCHO 2.898E+19 -2.20 3.185E+04 REV/ 1.250E+11 0.00 1.190E+04 / OCH2OCHO<=>HOCH2OCO 1.000E+11 0.00 1.400E+04 REV/ 2.746E+08 -0.79 2.008E+04 / HOCH2OCO<=>HOCH2O+CO 3.919E+18 -3.30 1.910E+04 REV/ 1.500E+11 0.00 4.800E+03 / HOCH2OCO<=>CH2OH+CO2 4.226E+16 -2.85 2.153E+04 REV/ 1.500E+11 0.00 3.572E+04 / CH3OCHO<=>CH2OCHO+H 8.241E+19 -1.15 1.025E+05 REV/ 1.000E+14 0.00 0.000E+00 / CH3OCHO<=>CH3OCO+H 1.325E+19 -1.00 1.001E+05 REV/ 1.000E+14 0.00 0.000E+00 / CH3OCHO<=>CH3OH+CO 1.000E+14 0.00 6.250E+04 REV/ 6.857E+04 1.99 5.051E+04 / CH3OCHO<=>CH3O+HCO 5.374E+16 -0.01 9.709E+04 REV/ 3.000E+13 0.00 0.000E+00 / CH3OCHO<=>CH3+OCHO 3.214E+17 -0.53 7.997E+04 REV/ 1.000E+13 0.00 0.000E+00 / CH3OCHO+O2<=>CH3OCO+HO2 1.000E+13 0.00 4.970E+04 REV/ 3.435E+10 0.29 4.610E+02 / CH3OCHO+O2<=>CH2OCHO+HO2 2.050E+13 0.00 5.200E+04 REV/ 1.132E+10 0.44 2.710E+02 / CH3OCHO+OH<=>CH3OCO+H2O 2.340E+07 1.61 -3.500E+01 REV/ 1.630E+05 2.15 2.031E+04 / CH3OCHO+OH<=>CH2OCHO+H2O 5.270E+09 0.97 1.586E+03 REV/ 5.904E+06 1.65 1.944E+04 / CH3OCHO+HO2<=>CH3OCO+H2O2 4.820E+03 2.60 1.391E+04 REV/ 1.827E+03 2.55 3.359E+03 / CH3OCHO+HO2<=>CH2OCHO+H2O2 2.380E+04 2.55 1.649E+04 REV/ 1.451E+03 2.64 3.453E+03 / CH3OCHO+O<=>CH3OCO+OH 2.755E+05 2.45 2.830E+03 REV/ 9.469E+01 3.07 6.868E+03 / CH3OCHO+O<=>CH2OCHO+OH 9.800E+05 2.43 4.750E+03 REV/ 5.417E+01 3.20 6.298E+03 / CH3OCHO+H<=>CH3OCO+H2 6.500E+05 2.40 4.471E+03 REV/ 4.256E+02 3.04 9.921E+03 / CH3OCHO+H<=>CH2OCHO+H2 6.650E+05 2.54 6.756E+03 REV/ 7.002E+01 3.33 9.716E+03 / CH3OCHO+CH3<=>CH3OCO+CH4 7.550E-01 3.46 5.481E+03 REV/ 4.512E-01 3.66 1.247E+04 / CH3OCHO+CH3<=>CH2OCHO+CH4 4.520E-01 3.65 7.154E+03 REV/ 4.344E-02 3.99 1.165E+04 / CH3OCHO+CH3O<=>CH3OCO+CH3OH 5.480E+11 0.00 5.000E+03 REV/ 7.707E+09 0.43 1.068E+04 / CH3OCHO+CH3O<=>CH2OCHO+CH3OH 2.170E+11 0.00 6.458E+03 REV/ 4.908E+08 0.58 9.645E+03 / CH3OCHO+CH3O2<=>CH3OCO+CH3O2H 4.820E+03 2.60 1.391E+04 REV/ 3.554E+04 2.10 1.764E+03 / CH3OCHO+CH3O2<=>CH2OCHO+CH3O2H 2.380E+04 2.55 1.649E+04 REV/ 2.822E+04 2.20 1.858E+03 / CH3OCHO+HCO<=>CH3OCO+CH2O 5.400E+06 1.90 1.701E+04 REV/ 5.990E+05 2.26 7.266E+03 / CH3OCHO+HCO<=>CH2OCHO+CH2O 1.025E+05 2.50 1.843E+04 REV/ 1.829E+03 3.00 6.201E+03 / CH2OCHO<=>CH3OCO 2.620E+11 -0.03 3.818E+04 REV/ 1.629E+12 -0.18 4.067E+04 / CH3OCO<=>CH3+CO2 7.978E+12 0.33 1.564E+04 REV/ 4.760E+07 1.54 3.470E+04 / CH3OCO<=>CH3O+CO 3.179E+13 0.46 2.340E+04 REV/ 1.550E+06 2.02 5.730E+03 / CH2OCHO<=>CH2O+HCO 4.661E+12 0.12 2.744E+04 REV/ 1.500E+11 0.00 1.190E+04 / CH3+C2H5(+M)<=>C3H8(+M) 1.880E+13 0.00 0.000E+00 !REV/ 1.600E+23 -1.83 9.031E+04 / LOW / 2.7100E+74 -1.6820E+01 1.3065E+04 / TROE / 1.5270E-01 2.9100E+02 2.7420E+03 7.7480E+03 / !TROE FALL-OFF REACTION H2/2/ H2O/6/ AR/.7/ CO/1.5/ CO2/2/ CH4/2/ C2H6/3/ HE/.7/ C3H8<=>NC3H7+H 3.719E+17 -0.36 1.012E+05 REV/ 1.000E+14 0.00 0.000E+00 / C3H8<=>IC3H7+H 2.346E+18 -0.67 9.867E+04 REV/ 1.000E+14 0.00 0.000E+00 / C3H8+O2<=>IC3H7+HO2 2.000E+13 0.00 4.964E+04 REV/ 1.786E+09 0.60 -1.590E+02 / C3H8+O2<=>NC3H7+HO2 6.000E+13 0.00 5.229E+04 REV/ 3.379E+10 0.28 -5.900E+01 / H+C3H8<=>H2+IC3H7 1.300E+06 2.40 4.471E+03 REV/ 2.212E+01 3.35 9.361E+03 / H+C3H8<=>H2+NC3H7 1.330E+06 2.54 6.756E+03 REV/ 1.428E+02 3.17 9.096E+03 / C3H8+O<=>IC3H7+OH 5.490E+05 2.50 3.140E+03 REV/ 4.904E+00 3.43 6.618E+03 / C3H8+O<=>NC3H7+OH 3.710E+06 2.40 5.505E+03 REV/ 2.091E+02 3.01 6.433E+03 / C3H8+OH<=>NC3H7+H2O 1.054E+10 0.97 1.586E+03 REV/ 1.204E+07 1.50 1.882E+04 / C3H8+OH<=>IC3H7+H2O 4.670E+07 1.61 -3.500E+01 REV/ 8.457E+03 2.45 1.975E+04 / C3H8+HO2<=>IC3H7+H2O2 5.600E+12 0.00 1.770E+04 REV/ 4.160E+11 0.00 7.426E+03 / C3H8+HO2<=>NC3H7+H2O2 1.680E+13 0.00 2.043E+04 REV/ 2.330E+12 0.00 9.826E+03 / CH3+C3H8<=>CH4+IC3H7 6.400E+04 2.17 7.520E+03 REV/ 9.942E+02 2.67 1.395E+04 / CH3+C3H8<=>CH4+NC3H7 9.040E-01 3.65 7.154E+03 REV/ 8.857E-02 3.84 1.103E+04 / IC3H7+C3H8<=>NC3H7+C3H8 3.000E+10 0.00 1.290E+04 REV/ 3.000E+10 0.00 1.290E+04 / C2H3+C3H8<=>C2H4+IC3H7 1.000E+11 0.00 1.040E+04 REV/ 1.310E+11 0.00 1.780E+04 / C2H3+C3H8<=>C2H4+NC3H7 1.000E+11 0.00 1.040E+04 REV/ 1.310E+11 0.00 1.780E+04 / C2H5+C3H8<=>C2H6+IC3H7 1.000E+11 0.00 1.040E+04 REV/ 3.630E+10 0.00 9.934E+03 / C2H5+C3H8<=>C2H6+NC3H7 1.000E+11 0.00 1.040E+04 REV/ 3.630E+10 0.00 9.934E+03 / C3H8+C3H5-A<=>NC3H7+C3H6 7.940E+11 0.00 2.050E+04 REV/ 5.372E+16 -1.33 1.340E+04 / C3H8+C3H5-A<=>IC3H7+C3H6 7.940E+11 0.00 1.620E+04 REV/ 5.372E+16 -1.33 9.095E+03 / C3H8+CH3O<=>NC3H7+CH3OH 3.000E+11 0.00 7.000E+03 REV/ 1.220E+10 0.00 9.182E+03 / C3H8+CH3O<=>IC3H7+CH3OH 3.000E+11 0.00 7.000E+03 REV/ 1.220E+10 0.00 9.182E+03 / CH3O2+C3H8<=>CH3O2H+NC3H7 1.700E+13 0.00 2.046E+04 REV/ 2.055E+13 -0.51 5.204E+03 / CH3O2+C3H8<=>CH3O2H+IC3H7 2.000E+12 0.00 1.700E+04 REV/ 3.833E+11 -0.19 4.294E+03 / C2H5O2+C3H8<=>C2H5O2H+NC3H7 1.700E+13 0.00 2.046E+04 REV/ 2.059E+13 -0.51 5.208E+03 / C2H5O2+C3H8<=>C2H5O2H+IC3H7 2.000E+12 0.00 1.700E+04 REV/ 3.840E+11 -0.19 4.298E+03 / NC3H7O2+C3H8<=>NC3H7O2H+NC3H7 1.700E+13 0.00 2.046E+04 REV/ 2.102E+13 -0.51 5.000E+03 / NC3H7O2+C3H8<=>NC3H7O2H+IC3H7 2.000E+12 0.00 1.700E+04 REV/ 3.920E+11 -0.20 4.090E+03 / IC3H7O2+C3H8<=>IC3H7O2H+NC3H7 1.700E+13 0.00 2.046E+04 REV/ 2.109E+13 -0.51 5.000E+03 / IC3H7O2+C3H8<=>IC3H7O2H+IC3H7 2.000E+12 0.00 1.700E+04 REV/ 3.934E+11 -0.20 4.090E+03 / C3H8+CH3CO3<=>IC3H7+CH3CO3H 2.000E+12 0.00 1.700E+04 REV/ 3.143E+10 0.30 8.660E+03 / C3H8+CH3CO3<=>NC3H7+CH3CO3H 1.700E+13 0.00 2.046E+04 REV/ 1.685E+12 -0.01 9.570E+03 / C3H8+O2CHO<=>NC3H7+HO2CHO 5.520E+04 2.55 1.648E+04 REV/ 1.187E-08 5.54 -1.920E+03 / C3H8+O2CHO<=>IC3H7+HO2CHO 1.475E+04 2.60 1.391E+04 REV/ 7.838E-06 4.65 -3.000E+01 / IC3H7<=>H+C3H6 5.437E+13 -0.01 3.796E+04 REV/ 2.640E+13 0.00 2.160E+03 / IC3H7+H<=>C2H5+CH3 2.000E+13 0.00 0.000E+00 REV/ 5.514E+07 1.16 8.360E+03 / IC3H7+O2<=>C3H6+HO2 4.500E-19 0.00 5.020E+03 REV/ 2.000E-19 0.00 1.750E+04 / IC3H7+OH<=>C3H6+H2O 2.410E+13 0.00 0.000E+00 REV/ 2.985E+12 0.57 8.382E+04 / IC3H7+O<=>CH3COCH3+H 4.818E+13 0.00 0.000E+00 REV/ 1.293E+16 -0.19 7.938E+04 / IC3H7+O<=>CH3CHO+CH3 4.818E+13 0.00 0.000E+00 REV/ 1.279E+11 0.80 8.648E+04 / NC3H7<=>CH3+C2H4 9.970E+40 -8.60 4.143E+04 REV/ 2.422E+34 -7.01 1.685E+04 / NC3H7<=>H+C3H6 8.780E+39 -8.10 4.658E+04 REV/ 2.070E+37 -7.39 1.202E+04 / NC3H7+O2<=>C3H6+HO2 3.000E-19 0.00 3.000E+03 REV/ 2.000E-19 0.00 1.750E+04 / C2H5CHO+NC3H7<=>C2H5CO+C3H8 1.700E+12 0.00 8.440E+03 REV/ 1.900E+14 0.00 1.879E+04 / C2H5CHO+IC3H7<=>C2H5CO+C3H8 1.700E+12 0.00 8.440E+03 REV/ 1.900E+14 0.00 1.879E+04 / C2H5CHO+C3H5-A<=>C2H5CO+C3H6 1.700E+12 0.00 8.440E+03 REV/ 1.000E+13 0.00 2.800E+04 / C3H6<=>C2H3+CH3 2.730E+62 -13.28 1.232E+05 REV/ 6.811E+53 -11.78 2.056E+04 / C3H6<=>C3H5-A+H 2.010E+61 -13.26 1.185E+05 REV/ 1.024E+61 -13.52 3.084E+04 / C3H6<=>C3H5-S+H 7.710E+69 -16.09 1.400E+05 REV/ 2.549E+67 -15.87 2.892E+04 / C3H6<=>C3H5-T+H 5.620E+71 -16.58 1.393E+05 REV/ 4.255E+68 -16.16 3.031E+04 / C3H6+O<=>C2H5+HCO 1.580E+07 1.76 -1.216E+03 REV/ 9.272E+01 2.72 2.312E+04 / C3H6+O<=>CH2CO+CH3+H 2.500E+07 1.76 7.600E+01 REV/ 0.000E+00 0.00 0.000E+00 / C3H6+O<=>CH3CHCO+H+H 2.500E+07 1.76 7.600E+01 REV/ 0.000E+00 0.00 0.000E+00 / C3H6+O<=>C3H5-A+OH 5.240E+11 0.70 5.884E+03 REV/ 5.593E+10 0.70 2.038E+04 / C3H6+O<=>C3H5-S+OH 1.200E+11 0.70 8.959E+03 REV/ 8.314E+07 1.18 2.300E+01 / C3H6+O<=>C3H5-T+OH 6.030E+10 0.70 7.632E+03 REV/ 9.569E+06 1.37 8.060E+02 / C3H6+OH<=>C3H5-A+H2O 3.120E+06 2.00 -2.980E+02 REV/ 6.750E+06 1.91 3.050E+04 / C3H6+OH<=>C3H5-S+H2O 2.110E+06 2.00 2.778E+03 REV/ 2.963E+04 2.39 1.015E+04 / C3H6+OH<=>C3H5-T+H2O 1.110E+06 2.00 1.451E+03 REV/ 3.571E+03 2.59 1.093E+04 / C3H6+HO2<=>C3H5-A+H2O2 9.640E+03 2.60 1.391E+04 REV/ 1.135E+06 1.92 1.382E+04 / C3H6+HO2<=>C3H5-S+H2O2 7.500E-21 0.00 1.257E+04 REV/ 2.308E-26 1.27 -1.342E+04 / C3H6+HO2<=>C3H5-T+H2O2 3.000E-21 0.00 9.930E+03 REV/ 9.234E-27 1.27 -1.406E+04 / C3H6+H<=>C3H5-A+H2 1.730E+05 2.50 2.492E+03 REV/ 3.518E+04 2.52 1.840E+04 / C3H6+H<=>C3H5-S+H2 8.040E+05 2.50 1.228E+04 REV/ 1.061E+03 3.00 4.756E+03 / C3H6+H<=>C3H5-T+H2 4.050E+05 2.50 9.794E+03 REV/ 1.224E+02 3.19 4.380E+03 / C3H6+H<=>C2H4+CH3 4.830E+34 -5.81 1.850E+04 REV/ 1.524E+29 -4.54 2.716E+04 / C3H6+O2<=>C3H5-A+HO2 4.000E+12 0.00 3.990E+04 REV/ 4.267E+12 -0.33 1.117E+03 / C3H6+O2<=>C3H5-S+HO2 2.000E+12 0.00 6.290E+04 REV/ 1.385E+10 0.15 6.890E+02 / C3H6+O2<=>C3H5-T+HO2 1.400E+12 0.00 6.070E+04 REV/ 2.220E+09 0.34 5.990E+02 / C3H6+CH3<=>C3H5-A+CH4 2.210E+00 3.50 5.675E+03 REV/ 4.102E+02 3.07 2.312E+04 / C3H6+CH3<=>C3H5-S+CH4 1.348E+00 3.50 1.285E+04 REV/ 1.624E+00 3.55 6.865E+03 / C3H6+CH3<=>C3H5-T+CH4 8.400E-01 3.50 1.166E+04 REV/ 2.318E-01 3.75 7.782E+03 / C3H6+C2H5<=>C3H5-A+C2H6 1.000E+11 0.00 9.800E+03 REV/ 5.369E+05 1.33 1.644E+04 / C3H6+CH3CO3<=>C3H5-A+CH3CO3H 3.240E+11 0.00 1.490E+04 REV/ 2.000E+10 0.00 1.500E+04 / C3H6+CH3O2<=>C3H5-A+CH3O2H 3.240E+11 0.00 1.490E+04 REV/ 2.000E+10 0.00 1.500E+04 / C3H6+HO2<=>C3H6O1-2+OH 1.290E+12 0.00 1.490E+04 REV/ 1.000E-10 0.00 0.000E+00 / C3H6+C2H5O2<=>C3H5-A+C2H5O2H 3.240E+11 0.00 1.490E+04 REV/ 2.000E+10 0.00 1.500E+04 / C3H6+NC3H7O2<=>C3H5-A+NC3H7O2H 3.240E+11 0.00 1.490E+04 REV/ 2.000E+10 0.00 1.500E+04 / C3H6+IC3H7O2<=>C3H5-A+IC3H7O2H 3.240E+11 0.00 1.490E+04 REV/ 2.000E+10 0.00 1.500E+04 / C3H6OH<=>C3H6+OH 4.336E+15 -0.81 2.791E+04 REV/ 9.930E+11 0.00 -9.600E+02 / HOC3H6O2<=>C3H6OH+O2 2.873E+19 -1.90 3.429E+04 REV/ 1.200E+11 0.00 -1.100E+03 / HOC3H6O2<=>CH3CHO+CH2O+OH 1.250E+10 0.00 1.890E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H5-A<=>C2H2+CH3 2.397E+48 -9.90 8.208E+04 REV/ 2.610E+46 -9.82 3.695E+04 / C3H5-A<=>C3H4-A+H 3.066E+13 0.21 6.128E+04 REV/ 2.400E+11 0.69 3.007E+03 / C3H5-A+HO2<=>C3H5O+OH 7.000E+12 0.00 -1.000E+03 REV/ 3.197E+12 0.06 1.144E+04 / C3H5-A+CH3O2<=>C3H5O+CH3O 7.000E+12 0.00 -1.000E+03 REV/ 1.990E+15 -0.74 1.702E+04 / C3H5-A+H<=>C3H4-A+H2 1.810E+13 0.00 0.000E+00 REV/ 5.657E+10 0.76 4.529E+04 / C3H5-A+CH3<=>C3H4-A+CH4 1.000E+11 0.00 0.000E+00 REV/ 4.921E+12 0.05 4.778E+04 / C3H5-A+C2H5<=>C2H6+C3H4-A 4.000E+11 0.00 0.000E+00 REV/ 1.802E+12 0.05 4.033E+04 / C3H5-A+C2H5<=>C2H4+C3H6 4.000E+11 0.00 0.000E+00 REV/ 6.937E+16 -1.33 5.280E+04 / C3H5-A+C2H3<=>C2H4+C3H4-A 1.000E+12 0.00 0.000E+00 REV/ 1.624E+13 0.05 4.819E+04 / C3H4-A+C3H6<=>C3H5-A+C3H5-A 8.391E+17 -1.29 3.369E+04 REV/ 1.000E+12 0.00 0.000E+00 / C3H5-A+O2<=>C3H4-A+HO2 2.180E+21 -2.85 3.076E+04 REV/ 3.575E+19 -2.44 2.136E+04 / C3H5-A+O2<=>CH2CHO+CH2O 7.140E+15 -1.21 2.105E+04 REV/ 4.944E+16 -1.40 8.862E+04 / C3H5-A+O2<=>C2H3CHO+OH 2.470E+13 -0.44 2.302E+04 REV/ 3.962E+13 -0.61 7.492E+04 / C3H5-A+O2<=>C2H2+CH2O+OH 9.720E+29 -5.71 2.145E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H5-S<=>C2H2+CH3 9.598E+39 -8.17 4.203E+04 REV/ 1.610E+40 -8.58 2.033E+04 / C3H5-S<=>C3H4-P+H 4.187E+15 -0.79 3.748E+04 REV/ 5.800E+12 0.00 3.100E+03 / C3H5-S+O2<=>CH3CHO+HCO 4.335E+12 0.00 0.000E+00 REV/ 1.611E+17 -1.27 9.653E+04 / C3H5-S+H<=>C3H4-A+H2 3.333E+12 0.00 0.000E+00 REV/ 7.977E+12 0.11 6.886E+04 / C3H5-S+CH3<=>C3H4-A+CH4 1.000E+11 0.00 0.000E+00 REV/ 6.253E+12 0.11 6.934E+04 / C3H5-T<=>C2H2+CH3 2.163E+40 -8.31 4.511E+04 REV/ 1.610E+40 -8.58 2.033E+04 / C3H5-T<=>C3H4-A+H 3.508E+14 -0.44 4.089E+04 REV/ 8.500E+12 0.00 2.000E+03 / C3H5-T<=>C3H4-P+H 1.075E+15 -0.60 3.849E+04 REV/ 6.500E+12 0.00 2.000E+03 / C3H5-T+O2<=>C3H4-A+HO2 1.890E+30 -5.59 1.554E+04 REV/ 2.085E+31 -5.86 2.746E+04 / C3H5-T+O2<=>CH3COCH2+O 3.810E+17 -1.36 5.580E+03 REV/ 2.000E+11 0.00 1.750E+04 / C3H5-T+O2<=>CH2O+CH3CO 3.710E+25 -3.96 7.043E+03 REV/ 1.872E+27 -4.43 1.012E+05 / C3H5-T+H<=>C3H4-P+H2 3.333E+12 0.00 0.000E+00 REV/ 2.138E+16 -0.88 7.105E+04 / C3H5-T+CH3<=>C3H4-P+CH4 1.000E+11 0.00 0.000E+00 REV/ 1.676E+16 -0.88 7.153E+04 / C3H4-A+M<=>C3H3+H+M 1.143E+17 0.00 7.000E+04 REV/ 1.798E+15 -0.38 1.061E+04 / C3H4-A<=>C3H4-P 1.202E+15 0.00 9.240E+04 REV/ 3.222E+18 -0.99 9.659E+04 / C3H4-A+O2<=>C3H3+HO2 4.000E+13 0.00 3.916E+04 REV/ 1.562E+11 0.26 8.910E+02 / C3H4-A+HO2<=>CH2CO+CH2+OH 4.000E+12 0.00 1.900E+04 REV/ 1.000E+00 0.00 0.000E+00 / C3H4-A+OH<=>CH2CO+CH3 3.120E+12 0.00 -3.970E+02 REV/ 1.806E+17 -1.38 3.607E+04 / C3H4-A+OH<=>C3H3+H2O 1.000E+07 2.00 1.000E+03 REV/ 7.919E+04 2.50 3.231E+04 / C3H4-A+O<=>C2H4+CO 7.800E+12 0.00 1.600E+03 REV/ 4.814E+08 1.24 1.210E+05 / C3H4-A+O<=>C2H2+CH2O 3.000E-03 4.61 -4.243E+03 REV/ 2.320E+02 3.23 8.119E+04 / C3H4-A+H<=>C3H3+H2 2.000E+07 2.00 5.000E+03 REV/ 1.489E+04 2.61 2.142E+04 / C3H4-A+CH3<=>C3H3+CH4 3.670E-02 4.01 6.830E+03 REV/ 2.493E-02 4.17 2.479E+04 / C3H4-A+C3H5-A<=>C3H3+C3H6 2.000E+11 0.00 7.700E+03 REV/ 2.644E+19 -2.71 4.214E+04 / C3H4-A+C2H<=>C3H3+C2H2 1.000E+13 0.00 0.000E+00 REV/ 1.420E+16 -1.38 5.382E+04 / C3H4-P+M<=>C3H3+H+M 1.143E+17 0.00 7.000E+04 REV/ 6.708E+11 0.61 6.420E+03 / C3H4-P<=>C2H+CH3 4.200E+16 0.00 1.000E+05 REV/ 1.018E+12 0.61 -1.600E+03 / C3H4-P+O2<=>HCCO+OH+CH2 1.000E+07 1.50 3.010E+04 REV/ 1.000E+00 0.00 0.000E+00 / C3H4-P+O2<=>C3H3+HO2 2.000E+13 0.00 4.160E+04 REV/ 3.128E+11 0.10 9.310E+02 / C3H4-P+HO2<=>C2H4+CO+OH 3.000E+12 0.00 1.900E+04 REV/ 1.000E+00 0.00 0.000E+00 / C3H4-P+OH<=>C3H3+H2O 1.000E+07 2.00 1.000E+03 REV/ 3.172E+05 2.34 2.991E+04 / C3H4-P+OH<=>CH2CO+CH3 5.000E-04 4.50 -1.000E+03 REV/ 1.079E-02 4.11 3.128E+04 / C3H4-P+O<=>CH2CO+CH2 3.200E-18 0.00 2.010E+03 REV/ 6.127E-18 -0.39 2.749E+04 / C3H4-P+O<=>C2H3+HCO 3.200E+12 0.00 2.010E+03 REV/ 2.548E+12 -0.39 3.235E+04 / C3H4-P+O<=>C2H4+CO 3.200E-18 0.00 2.010E+03 REV/ 1.440E-16 -0.39 1.232E+05 / C3H4-P+O<=>HCCO+CH3 9.600E+08 1.00 0.000E+00 REV/ 1.629E+05 1.17 2.000E+04 / C3H4-P+O<=>HCCO+CH2+H 3.200E-19 0.00 2.010E+03 REV/ 1.000E-30 0.00 0.000E+00 / C3H4-P+O<=>C3H3+OH 7.650E+08 1.50 8.600E+03 REV/ 2.177E+08 1.31 2.247E+04 / C3H4-P+H<=>C3H3+H2 2.000E+07 2.00 5.000E+03 REV/ 5.963E+04 2.45 1.902E+04 / C3H4-P+CH3<=>C3H3+CH4 1.500E+00 3.50 5.600E+03 REV/ 4.082E+00 3.50 2.116E+04 / C3H4-P+C2H<=>C3H3+C2H2 1.000E+12 0.00 0.000E+00 REV/ 5.297E+11 -0.39 4.963E+04 / C3H4-P+C2H3<=>C3H3+C2H4 1.000E+12 0.00 7.700E+03 REV/ 9.541E+11 -0.39 5.245E+04 / C3H4-P+C3H5-A<=>C3H3+C3H6 1.000E+12 0.00 7.700E+03 REV/ 4.931E+16 -1.73 3.795E+04 / C3H3+O<=>CH2O+C2H 1.000E+13 0.00 0.000E+00 REV/ 5.446E+14 0.00 3.161E+04 / C3H3+OH<=>C3H2+H2O 1.000E+13 0.00 0.000E+00 REV/ 1.343E+15 0.00 1.568E+04 / C3H3+O2<=>CH2CO+HCO 3.010E+10 0.00 2.870E+03 REV/ 4.881E+11 0.00 5.947E+04 / C3H3+CH3<=>C2H5+C2H 1.454E+15 -0.44 4.708E+04 REV/ 1.810E+13 0.00 0.000E+00 / C3H2+O2<=>HCO+HCCO 5.000E+13 0.00 0.000E+00 REV/ 1.805E+15 -0.79 7.174E+04 / C3H4-A+HO2<=>C2H4+CO+OH 1.000E+12 0.00 1.400E+04 REV/ 1.000E+00 0.00 0.000E+00 / C3H4-A+HO2<=>C3H3+H2O2 3.000E+13 0.00 1.400E+04 REV/ 1.551E+16 -1.38 4.400E+04 / C2H2+CH3<=>C3H4-P+H 6.136E+08 1.10 1.055E+04 REV/ 1.000E+14 0.00 4.000E+03 / C2H2+CH3<=>C3H4-A+H 6.740E+19 -2.08 3.159E+04 REV/ 4.400E+25 -3.34 2.264E+04 / C3H3+H<=>C3H2+H2 5.000E+13 0.00 0.000E+00 REV/ 1.773E+08 1.01 2.660E+03 / C3H2+OH<=>C2H2+HCO 5.000E+13 0.00 0.000E+00 REV/ 2.282E+16 -0.25 7.502E+04 / C3H2+O2<=>HCCO+CO+H 5.000E+13 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / CH3CHCO+OH<=>C2H5+CO2 1.730E+12 0.00 -1.010E+03 REV/ 0.000E+00 0.00 0.000E+00 / CH3CHCO+OH<=>SC2H4OH+CO 2.000E+12 0.00 -1.010E+03 REV/ 0.000E+00 0.00 0.000E+00 / CH3CHCO+H<=>C2H5+CO 4.400E+12 0.00 1.459E+03 REV/ 0.000E+00 0.00 0.000E+00 / CH3CHCO+O<=>CH3CHO+CO 3.200E+12 0.00 -4.370E+02 REV/ 0.000E+00 0.00 0.000E+00 / NC3H7+HO2<=>NC3H7O+OH 7.000E+12 0.00 -1.000E+03 REV/ 7.956E+15 -0.71 2.633E+04 / IC3H7+HO2<=>IC3H7O+OH 7.000E+12 0.00 -1.000E+03 REV/ 1.335E+16 -0.58 2.706E+04 / CH3O2+NC3H7<=>CH3O+NC3H7O 7.000E+12 0.00 -1.000E+03 REV/ 4.977E+14 -0.41 3.057E+04 / CH3O2+IC3H7<=>CH3O+IC3H7O 7.000E+12 0.00 -1.000E+03 REV/ 8.347E+14 -0.28 3.130E+04 / NC3H7O2<=>NC3H7+O2 3.063E+20 -1.64 3.571E+04 REV/ 4.520E+12 0.00 0.000E+00 / IC3H7O2<=>IC3H7+O2 3.978E+22 -2.19 3.790E+04 REV/ 7.540E+12 0.00 0.000E+00 / NC3H7O2+CH2O<=>NC3H7O2H+HCO 5.600E+12 0.00 1.360E+04 REV/ 8.000E+11 0.00 1.000E+04 / NC3H7O2+CH3CHO<=>NC3H7O2H+CH3CO 2.800E+12 0.00 1.360E+04 REV/ 1.000E+12 0.00 1.000E+04 / IC3H7O2+CH2O<=>IC3H7O2H+HCO 5.600E+12 0.00 1.360E+04 REV/ 8.000E+11 0.00 1.000E+04 / IC3H7O2+CH3CHO<=>IC3H7O2H+CH3CO 2.800E+12 0.00 1.360E+04 REV/ 1.000E+12 0.00 1.000E+04 / NC3H7O2+HO2<=>NC3H7O2H+O2 1.750E+10 0.00 -3.275E+03 REV/ 3.841E+13 -0.80 3.361E+04 / IC3H7O2+HO2<=>IC3H7O2H+O2 1.750E+10 0.00 -3.275E+03 REV/ 3.855E+13 -0.80 3.361E+04 / C2H4+NC3H7O2<=>C2H3+NC3H7O2H 1.130E+13 0.00 3.043E+04 REV/ 3.000E+12 0.00 1.150E+04 / C2H4+IC3H7O2<=>C2H3+IC3H7O2H 1.130E+13 0.00 3.043E+04 REV/ 3.000E+12 0.00 1.150E+04 / CH3OH+NC3H7O2<=>CH2OH+NC3H7O2H 6.300E+12 0.00 1.936E+04 REV/ 1.000E+09 0.00 1.000E+04 / CH3OH+IC3H7O2<=>CH2OH+IC3H7O2H 6.300E+12 0.00 1.936E+04 REV/ 1.000E+09 0.00 1.000E+04 / C2H3CHO+NC3H7O2<=>C2H3CO+NC3H7O2H 2.800E+12 0.00 1.360E+04 REV/ 1.000E+12 0.00 1.000E+04 / C2H3CHO+IC3H7O2<=>C2H3CO+IC3H7O2H 2.800E+12 0.00 1.360E+04 REV/ 1.000E+12 0.00 1.000E+04 / CH4+NC3H7O2<=>CH3+NC3H7O2H 1.120E+13 0.00 2.464E+04 REV/ 7.430E+11 0.00 5.500E+03 / CH4+IC3H7O2<=>CH3+IC3H7O2H 1.120E+13 0.00 2.464E+04 REV/ 7.430E+11 0.00 5.500E+03 / NC3H7O2+CH3O2<=>NC3H7O+CH3O+O2 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / IC3H7O2+CH3O2<=>IC3H7O+CH3O+O2 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / H2+NC3H7O2<=>H+NC3H7O2H 3.010E+13 0.00 2.603E+04 REV/ 4.800E+13 0.00 7.950E+03 / H2+IC3H7O2<=>H+IC3H7O2H 3.010E+13 0.00 2.603E+04 REV/ 4.800E+13 0.00 7.950E+03 / IC3H7O2+C2H6<=>IC3H7O2H+C2H5 1.700E+13 0.00 2.046E+04 REV/ 5.000E+11 0.00 6.500E+03 / NC3H7O2+C2H6<=>NC3H7O2H+C2H5 1.700E+13 0.00 2.046E+04 REV/ 5.000E+11 0.00 6.500E+03 / IC3H7O2+C2H5CHO<=>IC3H7O2H+C2H5CO 2.000E+11 0.00 9.500E+03 REV/ 5.000E+09 0.00 1.000E+04 / NC3H7O2+C2H5CHO<=>NC3H7O2H+C2H5CO 2.000E+11 0.00 9.500E+03 REV/ 5.000E+09 0.00 1.000E+04 / IC3H7O2+CH3CO3<=>IC3H7O+CH3CO2+O2 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / NC3H7O2+CH3CO3<=>NC3H7O+CH3CO2+O2 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / IC3H7O2+C2H5O2<=>IC3H7O+C2H5O+O2 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / NC3H7O2+C2H5O2<=>NC3H7O+C2H5O+O2 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / IC3H7O2+IC3H7O2<=>O2+IC3H7O+IC3H7O 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / NC3H7O2+NC3H7O2<=>O2+NC3H7O+NC3H7O 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / IC3H7O2+NC3H7O2<=>IC3H7O+NC3H7O+O2 1.400E+16 -1.61 1.860E+03 REV/ 0.000E+00 0.00 0.000E+00 / IC3H7O2+CH3<=>IC3H7O+CH3O 7.000E+12 0.00 -1.000E+03 REV/ 1.145E+11 0.70 2.672E+04 / IC3H7O2+C2H5<=>IC3H7O+C2H5O 7.000E+12 0.00 -1.000E+03 REV/ 1.628E+13 0.09 2.913E+04 / IC3H7O2+IC3H7<=>IC3H7O+IC3H7O 7.000E+12 0.00 -1.000E+03 REV/ 3.528E+13 0.24 2.954E+04 / IC3H7O2+NC3H7<=>IC3H7O+NC3H7O 7.000E+12 0.00 -1.000E+03 REV/ 2.103E+13 0.10 2.881E+04 / IC3H7O2+C3H5-A<=>IC3H7O+C3H5O 7.000E+12 0.00 -1.000E+03 REV/ 8.452E+09 0.88 1.392E+04 / NC3H7O2+CH3<=>NC3H7O+CH3O 7.000E+12 0.00 -1.000E+03 REV/ 5.315E+12 0.01 2.818E+04 / NC3H7O2+C2H5<=>NC3H7O+C2H5O 7.000E+12 0.00 -1.000E+03 REV/ 7.557E+14 -0.59 3.059E+04 / NC3H7O2+IC3H7<=>NC3H7O+IC3H7O 7.000E+12 0.00 -1.000E+03 REV/ 1.637E+15 -0.45 3.100E+04 / NC3H7O2+NC3H7<=>NC3H7O+NC3H7O 7.000E+12 0.00 -1.000E+03 REV/ 9.760E+14 -0.58 3.027E+04 / NC3H7O2+C3H5-A<=>NC3H7O+C3H5O 7.000E+12 0.00 -1.000E+03 REV/ 3.922E+11 0.19 1.538E+04 / NC3H7O2H<=>NC3H7O+OH 1.500E+16 0.00 4.250E+04 REV/ 1.146E+08 1.72 -2.772E+03 / IC3H7O2H<=>IC3H7O+OH 9.450E+15 0.00 4.260E+04 REV/ 1.550E+06 2.41 -4.132E+03 / NC3H7O<=>C2H5+CH2O 2.722E+21 -2.45 1.697E+04 REV/ 1.000E+11 0.00 3.496E+03 / NC3H7O<=>C2H5CHO+H 8.886E+10 0.75 2.106E+04 REV/ 4.000E+12 0.00 6.260E+03 / IC3H7O<=>CH3+CH3CHO 5.328E+19 -1.70 1.714E+04 REV/ 1.000E+11 0.00 9.256E+03 / IC3H7O<=>CH3COCH3+H 8.658E+14 -0.48 2.008E+04 REV/ 2.000E+12 0.00 7.270E+03 / IC3H7O+O2<=>CH3COCH3+HO2 9.090E+09 0.00 3.900E+02 REV/ 1.000E+11 0.00 3.200E+04 / NC3H7O2<=>C3H6OOH1-2 6.000E+11 0.00 2.685E+04 REV/ 1.117E+08 0.58 1.172E+04 / NC3H7O2<=>C3H6OOH1-3 1.125E+11 0.00 2.440E+04 REV/ 2.716E+11 -0.51 8.936E+03 / IC3H7O2<=>C3H6OOH2-1 1.800E+12 0.00 2.940E+04 REV/ 1.122E+10 0.12 1.181E+04 / IC3H7O2<=>C3H6OOH2-2 1.230E+35 -6.96 4.888E+04 REV/ 2.384E+34 -7.06 4.494E+04 / C3H6OOH1-2<=>C3H6O1-2+OH 6.000E+11 0.00 2.200E+04 REV/ 1.150E+11 0.49 3.837E+04 / C3H6OOH1-3<=>C3H6O1-3+OH 7.500E+10 0.00 1.525E+04 REV/ 1.186E+06 1.76 2.871E+04 / C3H6OOH2-1<=>C3H6O1-2+OH 6.000E+11 0.00 2.200E+04 REV/ 2.780E+08 1.19 3.609E+04 / C3H6OOH1-2<=>C3H6+HO2 7.822E+15 -1.30 1.571E+04 REV/ 1.000E+11 0.00 1.075E+04 / C3H6OOH2-1<=>C3H6+HO2 3.234E+18 -2.00 1.898E+04 REV/ 1.000E+11 0.00 1.175E+04 / C3H6OOH1-3<=>OH+CH2O+C2H4 3.035E+15 -0.79 2.740E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H6OOH2-1<=>C2H3OOH+CH3 6.540E+27 -5.14 3.832E+04 REV/ 4.460E+22 -4.24 1.063E+04 / C3H6OOH1-2<=>C2H4+CH2O+OH 1.310E+33 -7.01 4.812E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H6OOH2-2<=>CH3COCH3+OH 9.000E+14 0.00 1.500E+03 REV/ 1.021E+14 0.31 3.675E+04 / C3H6OOH1-2O2<=>C3H6OOH1-2+O2 2.391E+25 -2.94 4.010E+04 REV/ 5.000E+12 0.00 0.000E+00 / C3H6OOH1-3O2<=>C3H6OOH1-3+O2 2.853E+20 -1.63 3.569E+04 REV/ 4.520E+12 0.00 0.000E+00 / C3H6OOH2-1O2<=>C3H6OOH2-1+O2 5.227E+22 -2.24 3.782E+04 REV/ 4.520E+12 0.00 0.000E+00 / C3H6OOH1-2O2<=>C3KET12+OH 6.000E+11 0.00 2.640E+04 REV/ 9.249E+04 1.33 4.892E+04 / C3H6OOH1-3O2<=>C3KET13+OH 7.500E+10 0.00 2.140E+04 REV/ 4.101E+03 1.50 4.474E+04 / C3H6OOH2-1O2<=>C3KET21+OH 3.000E+11 0.00 2.385E+04 REV/ 1.397E+03 1.83 4.975E+04 / C3H6OOH2-1O2<=>C3H51-2,3OOH 1.125E+11 0.00 2.440E+04 REV/ 2.042E+09 0.02 9.850E+03 / C3H6OOH1-2O2<=>C3H51-2,3OOH 9.000E+11 0.00 2.940E+04 REV/ 1.634E+10 0.02 1.485E+04 / C3H51-2,3OOH<=>AC3H5OOH+HO2 2.560E+13 -0.49 1.777E+04 REV/ 3.180E+15 -1.16 1.204E+04 / C3H52-1,3OOH<=>C3H6OOH1-3O2 9.203E+08 0.26 1.685E+04 REV/ 6.000E+11 0.00 2.685E+04 / C3H52-1,3OOH<=>AC3H5OOH+HO2 1.150E+14 -0.63 1.725E+04 REV/ 1.564E+11 0.12 1.020E+04 / C3KET12<=>CH3CHO+HCO+OH 9.450E+15 0.00 4.300E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3KET13<=>CH2O+CH2CHO+OH 1.000E+16 0.00 4.300E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3KET21<=>CH2O+CH3CO+OH 1.000E+16 0.00 4.300E+04 REV/ 0.000E+00 0.00 0.000E+00 / AC3H5OOH<=>C3H5O+OH 3.880E+19 -1.46 4.537E+04 REV/ 2.000E+13 0.00 0.000E+00 / C3H5O<=>C2H3CHO+H 1.000E+14 0.00 2.910E+04 REV/ 1.676E+14 -0.16 1.969E+04 / C3H5O<=>C2H3+CH2O 1.464E+20 -1.97 3.509E+04 REV/ 1.500E+11 0.00 1.060E+04 / C3H5O+O2<=>C2H3CHO+HO2 1.000E+12 0.00 6.000E+03 REV/ 1.288E+11 0.00 3.200E+04 / C2H3OOH<=>CH2CHO+OH 8.400E+14 0.00 4.300E+04 REV/ 1.000E+11 0.00 0.000E+00 / C3H6O1-2<=>C2H4+CH2O 6.000E+14 0.00 6.000E+04 REV/ 2.970E+11 1.00 3.108E+04 / C3H6O1-2+OH<=>CH2O+C2H3+H2O 5.000E+12 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-2+H<=>CH2O+C2H3+H2 2.630E+07 2.00 5.000E+03 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-2+O<=>CH2O+C2H3+OH 8.430E+13 0.00 5.200E+03 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-2+HO2<=>CH2O+C2H3+H2O2 1.000E+13 0.00 1.500E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-2+CH3O2<=>CH2O+C2H3+CH3O2H 1.000E+13 0.00 1.900E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-2+CH3<=>CH2O+C2H3+CH4 2.000E+11 0.00 1.000E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-3<=>C2H4+CH2O 6.000E+14 0.00 6.000E+04 REV/ 2.970E+11 0.00 3.108E+04 / C3H6O1-3+OH<=>CH2O+C2H3+H2O 5.000E+12 0.00 0.000E+00 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-3+O<=>CH2O+C2H3+OH 8.430E+13 0.00 5.200E+03 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-3+H<=>CH2O+C2H3+H2 2.630E+07 2.00 5.000E+03 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-3+CH3O2<=>CH2O+C2H3+CH3O2H 1.000E+13 0.00 1.900E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-3+HO2<=>CH2O+C2H3+H2O2 1.000E+13 0.00 1.500E+04 REV/ 0.000E+00 0.00 0.000E+00 / C3H6O1-3+CH3<=>CH2O+C2H3+CH4 2.000E+11 0.00 1.000E+04 REV/ 0.000E+00 0.00 0.000E+00 / MB<=>MB4J+H 1.860E+17 -0.34 1.012E+05 REV/ 1.000E+14 0.00 0.000E+00 / MB<=>MB3J+H 4.335E+18 -0.74 9.876E+04 REV/ 1.000E+14 0.00 0.000E+00 / MB<=>MB2J+H 5.972E+14 0.24 9.338E+04 REV/ 1.000E+14 0.00 0.000E+00 / MB<=>MBMJ+H 1.676E+17 -0.38 1.005E+05 REV/ 1.000E+14 0.00 0.000E+00 / MB(+M)<=>CH3COOCH3+C2H4(+M) 4.000E+12 0.00 6.800E+04 !REV/ 6.202E+03 1.99 4.448E+04 / LOW / 2.4390E+76 -1.7550E+01 6.0570E+04 / TROE / 9.5460E-01 9.9990E+09 1.0000E+00 7.5960E+07 / !TROE FALL-OFF REACTION MB(+M)<=>MP3J+CH3(+M) 7.213E+18 -0.89 8.721E+04 !REV/ 1.250E+09 0.94 -2.800E+03 / LOW / 6.5310E+68 -1.4720E+01 8.4650E+04 / TROE / 1.6420E-01 3.7060E+02 9.8710E+09 9.9240E+09 / !TROE FALL-OFF REACTION MB(+M)<=>BAOJ+CH3(+M) 1.915E+21 -1.59 1.001E+05 !REV/ 3.751E+09 0.94 -2.780E+03 / LOW / 3.3660E+57 -1.1730E+01 9.2670E+04 / TROE / 7.3660E-01 8.8290E+09 3.9780E+02 8.2140E+09 / !TROE FALL-OFF REACTION MB(+M)<=>ME2J+C2H5(+M) 3.383E+20 -1.41 8.483E+04 !REV/ 1.244E+11 0.45 -8.500E+02 / LOW / 5.9940E+72 -1.5840E+01 8.3090E+04 / TROE / 1.4550E-01 3.6140E+02 6.9070E+09 1.7860E+09 / !TROE FALL-OFF REACTION MB(+M)<=>CH3OCO+NC3H7(+M) 2.045E+24 -2.24 9.302E+04 !REV/ 6.626E+11 0.31 5.000E+01 / LOW / 9.4010E+67 -1.4390E+01 8.8050E+04 / TROE / 2.0500E-01 4.0240E+02 9.9520E+09 6.6980E+08 / !TROE FALL-OFF REACTION MB(+M)<=>NC3H7CO+CH3O(+M) 3.713E+21 -1.38 9.890E+04 !REV/ 3.412E+09 0.95 -1.287E+03 / LOW / 9.7710E+58 -1.1840E+01 9.1820E+04 / TROE / 7.4760E-01 9.4740E+09 4.0350E+02 5.0000E+09 / !TROE FALL-OFF REACTION MB+C2H3<=>C2H4+MB4J 5.010E+11 0.00 1.800E+04 REV/ 3.407E+11 0.11 2.812E+04 / MB+C2H5<=>C2H6+MB4J 5.010E+10 0.00 1.340E+04 REV/ 1.165E+11 -0.06 1.353E+04 / MB+CH3<=>CH4+MB4J 4.520E-01 3.65 7.154E+03 REV/ 8.858E-02 3.82 1.105E+04 / MB+CH3O<=>CH3OH+MB4J 1.581E+11 0.00 7.000E+03 REV/ 7.291E+08 0.41 9.587E+03 / MB+CH3O2<=>CH3O2H+MB4J 8.400E+12 0.00 2.044E+04 REV/ 2.031E+13 -0.52 5.204E+03 / MB+H<=>H2+MB4J 9.400E+04 2.75 6.280E+03 REV/ 2.018E+01 3.37 8.640E+03 / MB+HO2<=>H2O2+MB4J 4.040E+04 2.50 1.669E+04 REV/ 5.021E+03 2.42 3.050E+03 / MB+O<=>OH+MB4J 9.650E+04 2.68 3.716E+03 REV/ 1.088E+01 3.28 4.664E+03 / MB+O2<=>HO2+MB4J 3.000E+13 0.00 5.280E+04 REV/ 3.379E+10 0.27 4.710E+02 / MB+OH<=>H2O+MB4J 5.250E+09 0.97 1.590E+03 REV/ 1.199E+07 1.48 1.884E+04 / MB+C2H3<=>C2H4+MB3J 4.000E+11 0.00 1.680E+04 REV/ 1.167E+10 0.51 2.936E+04 / MB+C2H5<=>C2H6+MB3J 5.000E+10 0.00 1.040E+04 REV/ 4.988E+09 0.34 1.297E+04 / MB+CH3<=>CH4+MB3J 2.705E+04 2.26 7.287E+03 REV/ 2.274E+02 2.83 1.363E+04 / MB+CH3O<=>CH3OH+MB3J 1.095E+11 0.00 5.000E+03 REV/ 2.166E+07 0.81 1.003E+04 / MB+CH3O2<=>CH3O2H+MB3J 5.600E+12 0.00 1.769E+04 REV/ 5.808E+11 -0.12 4.894E+03 / MB+H<=>H2+MB3J 1.300E+06 2.40 4.471E+03 REV/ 1.197E+01 3.42 9.271E+03 / MB+HO2<=>H2O2+MB3J 5.880E+04 2.50 1.486E+04 REV/ 3.135E+02 2.82 3.662E+03 / MB+O<=>OH+MB3J 4.770E+04 2.71 2.106E+03 REV/ 2.306E-01 3.71 5.494E+03 / MB+O2<=>HO2+MB3J 2.000E+13 0.00 5.105E+04 REV/ 9.664E+08 0.67 1.161E+03 / MB+OH<=>H2O+MB3J 4.680E+07 1.61 -3.500E+01 REV/ 4.586E+03 2.52 1.966E+04 / MB+C2H3<=>C2H4+MB2J 4.000E+11 0.00 1.430E+04 REV/ 8.469E+13 -0.47 3.224E+04 / MB+C2H5<=>C2H6+MB2J 2.000E+11 0.00 7.900E+03 REV/ 1.448E+14 -0.65 1.585E+04 / MB+CH3<=>CH4+MB2J 2.000E+11 0.00 7.900E+03 REV/ 1.220E+13 -0.41 1.962E+04 / MB+CH3O<=>CH3OH+MB2J 3.800E+10 0.00 2.800E+03 REV/ 5.456E+10 -0.18 1.321E+04 / MB+CH3O2<=>CH3O2H+MB2J 4.000E+12 0.00 1.400E+04 REV/ 3.011E+15 -1.11 6.584E+03 / MB+H<=>H2+MB2J 2.520E+14 0.00 7.300E+03 REV/ 1.685E+13 0.03 1.748E+04 / MB+HO2<=>H2O2+MB2J 3.000E+04 2.50 1.226E+04 REV/ 1.161E+06 1.84 6.439E+03 / MB+O<=>OH+MB2J 2.200E+13 0.00 3.280E+03 REV/ 7.720E+11 0.01 1.205E+04 / MB+O2<=>HO2+MB2J 4.000E+13 0.00 4.130E+04 REV/ 1.403E+13 -0.32 -3.209E+03 / MB+OH<=>H2O+MB2J 1.146E+11 0.51 6.300E+01 REV/ 8.152E+10 0.44 2.514E+04 / MB+C2H3<=>C2H4+MBMJ 5.010E+11 0.00 1.800E+04 REV/ 3.779E+11 0.15 2.879E+04 / MB+C2H5<=>C2H6+MBMJ 5.010E+10 0.00 1.340E+04 REV/ 1.292E+11 -0.03 1.420E+04 / MB+CH3<=>CH4+MBMJ 4.520E-01 3.65 7.154E+03 REV/ 9.826E-02 3.86 1.172E+04 / MB+CH3O<=>CH3OH+MBMJ 1.581E+11 0.00 7.000E+03 REV/ 8.088E+08 0.44 1.026E+04 / MB+CH3O2<=>CH3O2H+MBMJ 8.400E+12 0.00 2.044E+04 REV/ 2.253E+13 -0.48 5.874E+03 / MB+H<=>H2+MBMJ 9.400E+04 2.75 6.280E+03 REV/ 2.239E+01 3.41 9.310E+03 / MB+HO2<=>H2O2+MBMJ 4.040E+04 2.50 1.669E+04 REV/ 5.570E+03 2.46 3.720E+03 / MB+O<=>OH+MBMJ 9.650E+04 2.68 3.716E+03 REV/ 1.206E+01 3.32 5.334E+03 / MB+O2<=>HO2+MBMJ 3.000E+13 0.00 5.280E+04 REV/ 3.749E+10 0.31 1.141E+03 / MB+OH<=>H2O+MBMJ 5.250E+09 0.97 1.590E+03 REV/ 1.330E+07 1.52 1.951E+04 / BAOJ<=>CO2+NC3H7 1.399E+15 -0.67 9.720E+03 REV/ 1.000E+11 0.00 3.936E+04 / MB2J<=>C2H5CHCO+CH3O 6.025E+13 0.38 5.359E+04 REV/ 1.420E+03 2.67 6.850E+03 / MB2J<=>MB2D+H 9.730E+14 -0.27 3.940E+04 REV/ 2.500E+11 0.51 2.620E+03 / MB2J<=>MP2D+CH3 1.077E+14 0.40 3.452E+04 REV/ 1.760E+04 2.48 6.130E+03 / MB3J<=>C3H6+CH3OCO 8.138E+12 0.35 3.359E+04 REV/ 8.800E+03 2.48 6.130E+03 / MB3J<=>MB2D+H 1.340E+11 0.72 3.402E+04 REV/ 2.500E+11 0.51 2.620E+03 / MB3J<=>MB3D+H 1.112E+11 0.69 3.791E+04 REV/ 4.240E+11 0.51 1.230E+03 / MB4J<=>C2H4+ME2J 3.472E+10 0.84 2.610E+04 REV/ 1.320E+04 2.48 6.130E+03 / MB4J<=>MB3D+H 1.529E+12 0.29 3.686E+04 REV/ 2.500E+11 0.51 2.620E+03 / ME2J<=>CH2CO+CH3O 5.493E+19 -1.53 4.321E+04 REV/ 5.000E+11 0.00 -1.000E+03 / MP3J<=>C2H4+CH3OCO 2.907E+13 0.17 3.367E+04 REV/ 1.320E+04 2.48 6.130E+03 / MP3J<=>MP2D+H 1.584E+12 0.50 3.438E+04 REV/ 2.500E+11 0.51 2.620E+03 / NC3H7CO<=>C2H5CHCO+H 5.822E+10 0.79 4.255E+04 REV/ 2.500E+11 0.51 2.620E+03 / NC3H7CO<=>CH2CO+C2H5 3.624E+09 1.41 3.583E+04 REV/ 1.320E+04 2.48 6.130E+03 / MBMJ<=>NC3H7CO+CH2O 8.419E+22 -2.33 4.595E+04 REV/ 2.002E+12 0.00 2.400E+04 / MB4J<=>MB2J 5.440E+08 1.16 2.904E+04 REV/ 1.694E+11 0.57 3.686E+04 / MB4J<=>MB3J 1.652E+10 0.94 3.933E+04 REV/ 7.086E+08 1.34 4.177E+04 / MB4J<=>MBMJ 4.565E+09 -0.55 1.882E+04 REV/ 5.064E+09 -0.51 1.949E+04 / MB3J<=>MBMJ 9.219E+10 -0.66 1.389E+04 REV/ 2.384E+12 -1.02 1.212E+04 / MB3J<=>MB2J 4.274E+09 1.23 3.676E+04 REV/ 3.102E+13 0.24 4.214E+04 / MB2J<=>MBMJ 2.800E+12 -0.86 2.431E+04 REV/ 9.974E+09 -0.24 1.716E+04 / MB2D+CH3<=>C5H7O2+CH4 1.000E+12 0.00 7.300E+03 REV/ 3.473E+14 -0.14 2.252E+04 / MB3D+CH3<=>C5H7O2+CH4 1.000E+12 0.00 7.300E+03 REV/ 1.699E+14 -0.17 2.780E+04 / MB2D+H<=>C5H7O2+H2 3.700E+13 0.00 3.900E+03 REV/ 4.919E+14 -0.14 1.864E+04 / MB3D+H<=>C5H7O2+H2 3.700E+13 0.00 3.900E+03 REV/ 2.407E+14 -0.17 2.392E+04 / C5H7O2+OH<=>MB2D+O 7.000E+11 0.00 2.990E+04 REV/ 1.199E+11 0.14 1.726E+04 / C5H7O2+OH<=>MB3D+O 7.000E+11 0.00 2.990E+04 REV/ 2.450E+11 0.17 1.198E+04 / C5H7O2<=>CH2CHCHCO+CH3O 2.500E+13 0.00 4.500E+04 REV/ 3.643E+08 0.48 -3.137E+03 / MB2D+OH<=>C5H7O2+H2O 3.000E+13 0.00 1.230E+03 REV/ 1.727E+15 -0.14 3.112E+04 / MB3D+OH<=>C5H7O2+H2O 3.000E+13 0.00 1.230E+03 REV/ 8.449E+14 -0.17 3.640E+04 / MB2D+HO2<=>C5H7O2+H2O2 1.500E+11 0.00 1.419E+04 REV/ 5.125E+13 -0.47 1.262E+04 / MB3D+HO2<=>C5H7O2+H2O2 1.500E+11 0.00 1.419E+04 REV/ 2.508E+13 -0.49 1.790E+04 / MB3OH4J<=>MB3D+OH 1.929E+17 -1.16 3.054E+04 REV/ 2.760E+12 0.00 -1.042E+03 / MB2OH3J<=>MB2D+OH 4.620E+16 -0.84 2.646E+04 REV/ 2.760E+12 0.00 -1.042E+03 / MP2OH3J<=>MP2D+OH 7.297E-13 -1.11 2.691E+04 REV/ 5.745E-19 0.18 -1.012E+03 / MB3OH4OO<=>MB3OH4J+O2 3.851E+18 -1.37 3.480E+04 REV/ 1.000E+12 0.00 -1.100E+03 / MB2OH3OO<=>MB2OH3J+O2 1.122E+21 -1.95 3.670E+04 REV/ 1.000E+12 0.00 -1.100E+03 / MP2OH3OO<=>MP2OH3J+O2 4.589E+18 -1.40 3.489E+04 REV/ 1.000E+12 0.00 -1.100E+03 / MB3OH4OO<=>MP3*O+OH+CH2O 1.000E+12 0.00 2.868E+04 REV/ 0.000E+00 0.00 0.000E+00 / MB2OH3OO<=>ME2*O+OH+CH3CHO 1.000E+12 0.00 2.868E+04 REV/ 0.000E+00 0.00 0.000E+00 / MP2OH3OO<=>ME2*O+OH+CH2O 1.000E+12 0.00 2.868E+04 REV/ 0.000E+00 0.00 0.000E+00 / MB3D+O<=>MP3J+HCO 1.580E+07 1.76 -1.216E+03 REV/ 2.190E+05 1.82 2.776E+04 / MB2D+O<=>ME2J+CH3CO 1.580E+07 1.76 -1.216E+03 REV/ 1.248E+04 2.46 3.134E+04 / MP2D+O<=>ME2J+HCO 1.580E+07 1.76 -1.216E+03 REV/ 3.126E+07 1.60 2.871E+04 / MB3D+O<=>ME2J+CH2CHO 2.505E+07 1.76 7.600E+01 REV/ 8.937E+05 2.04 3.268E+04 / MB2D+O<=>CH3OCO+CH3CHCHO 5.010E+07 1.76 7.600E+01 REV/ 7.808E+02 2.97 2.250E+04 / DUP MP2D+O<=>CH3OCO+CH2CHO 5.010E+07 1.76 7.600E+01 REV/ 2.212E+03 2.92 2.263E+04 / CH2CHCHCO+H<=>CJHCHCHCO+H2 4.210E-03 4.62 2.583E+03 REV/ 2.434E-03 4.38 -3.170E+03 / CH2CHCHCO+OH<=>CJHCHCHCO+H2O 1.010E+13 0.00 5.955E+03 REV/ 2.528E+13 -0.24 1.536E+04 / CH2CHCHCO+CH3<=>CJHCHCHCO+CH4 3.310E+00 3.70 9.500E+03 REV/ 4.999E+01 3.46 4.227E+03 / CH2CHCHCO+O<=>CJHCHCHCO+OH 1.200E+11 0.70 8.959E+03 REV/ 3.047E+10 0.46 1.111E+03 / CH2CHCHCO+HO2<=>CJHCHCHCO+H2O2 8.500E+13 0.00 3.043E+04 REV/ 1.263E+15 -0.57 8.369E+03 / CJHCHCHCO<=>C2H2+HCCO 7.623E+46 -9.64 6.102E+04 REV/ 1.610E+40 -8.58 2.033E+04 / CH2CHCHCO<=>C2H3+HCCO 1.895E+20 -0.82 1.120E+05 REV/ 8.000E+12 0.00 0.000E+00 / CH2CHCHCO+H<=>CO+C3H5-A 1.100E+13 0.00 3.400E+03 REV/ 8.133E+09 0.74 4.605E+04 / CH2CHCHCO+H<=>C2H4+HCCO 1.100E+13 0.00 3.400E+03 REV/ 1.288E+08 0.65 -1.823E+03 / CH2CHCHCO+OH<=>HCCO+CH3CHO 3.730E+12 0.00 -1.013E+03 REV/ 1.927E+07 0.96 5.590E+02 / CH2CHCHCO+OH<=>CH3CHCHO+CO 3.730E+12 0.00 -1.013E+03 REV/ 1.758E+10 0.88 4.242E+04 / MB2D<=>CH3+MP2D3J 1.747E+18 -0.58 1.001E+05 REV/ 1.000E+13 0.00 0.000E+00 / MB3D<=>C2H3+ME2J 2.175E+17 -0.54 9.005E+04 REV/ 1.000E+13 0.00 0.000E+00 / MP2D<=>C2H3+CH3OCO 1.758E+20 -1.42 1.001E+05 REV/ 1.000E+13 0.00 0.000E+00 / ME2*O<=>HCO+CH3OCO 7.733E+21 -1.91 7.696E+04 REV/ 1.000E+13 0.00 0.000E+00 / MB4*O<=>HCO+MP3J 2.046E+20 -1.22 8.224E+04 REV/ 1.000E+13 0.00 0.000E+00 / MBM*O<=>NC3H7+CHOOCO 2.512E+25 -1.85 8.111E+04 REV/ 1.000E+13 0.00 0.000E+00 / MP3*O<=>CH2CHO+CH3OCO 4.249E+22 -2.16 8.551E+04 REV/ 1.000E+13 0.00 0.000E+00 / C2H5CHCO<=>CH3+C2H3CO 5.378E+17 -0.77 6.902E+04 REV/ 1.000E+13 0.00 0.000E+00 / C2H5CHCO+OH<=>NC3H7+CO2 3.730E+12 0.00 -1.010E+03 REV/ 0.000E+00 0.00 0.000E+00 / C2H5CHCO+H<=>NC3H7+CO 4.400E+12 0.00 1.459E+03 REV/ 0.000E+00 0.00 0.000E+00 / C2H5CHCO+O<=>C3H6+CO2 3.200E+12 0.00 -4.370E+02 REV/ 0.000E+00 0.00 0.000E+00 / HO2+MB2J<=>OH+MB2O 1.332E+14 -0.59 2.553E+03 REV/ 5.936E+15 -0.97 2.484E+04 / HO2+MB3J<=>OH+MB3O 4.026E+13 -0.22 -1.570E+02 REV/ 2.529E+18 -1.40 2.865E+04 / HO2+MB4J<=>OH+MB4O 4.057E+13 -0.23 -1.470E+02 REV/ 1.693E+16 -0.76 2.673E+04 / HO2+MBMJ<=>OH+MBMO 4.042E+13 -0.23 -1.470E+02 REV/ 3.107E+16 -0.80 3.814E+04 / CH3O2+MB2J<=>CH3O+MB2O 2.080E+17 -1.47 3.073E+03 REV/ 5.798E+17 -1.55 2.960E+04 / CH3O2+MB3J<=>CH3O+MB3O 6.286E+16 -1.10 3.630E+02 REV/ 2.470E+20 -1.98 3.341E+04 / CH3O2+MB4J<=>CH3O+MB4O 6.336E+16 -1.10 3.730E+02 REV/ 1.654E+18 -1.34 3.149E+04 / CH3O2+MBMJ<=>CH3O+MBMO 6.311E+16 -1.11 3.730E+02 REV/ 3.034E+18 -1.38 4.290E+04 / C2H5O2+MB2J<=>C2H5O+MB2O 6.035E+11 0.31 -2.610E+02 REV/ 3.795E+14 -0.62 2.744E+04 / C2H5O2+MB3J<=>C2H5O+MB3O 1.824E+11 0.67 -2.971E+03 REV/ 1.617E+17 -1.06 3.125E+04 / C2H5O2+MB4J<=>C2H5O+MB4O 1.839E+11 0.68 -2.961E+03 REV/ 1.083E+15 -0.41 2.933E+04 / C2H5O2+MBMJ<=>C2H5O+MBMO 1.831E+11 0.68 -2.961E+03 REV/ 1.986E+15 -0.45 4.074E+04 / IC3H7O2+MB3J<=>IC3H7O+MB3O 7.672E+14 -0.82 1.300E+02 REV/ 1.274E+17 -1.18 3.142E+04 / IC3H7O2+MB4J<=>IC3H7O+MB4O 7.735E+14 -0.82 1.400E+02 REV/ 8.533E+14 -0.54 2.950E+04 / IC3H7O2+MBMJ<=>IC3H7O+MBMO 7.703E+14 -0.82 1.400E+02 REV/ 1.565E+15 -0.58 4.091E+04 / NC3H7O2+MB2J<=>NC3H7O+MB2O 5.744E+13 -0.35 1.190E+03 REV/ 3.140E+14 -0.60 2.742E+04 / NC3H7O2+MB3J<=>NC3H7O+MB3O 1.736E+13 0.02 -1.520E+03 REV/ 1.338E+17 -1.03 3.123E+04 / NC3H7O2+MB4J<=>NC3H7O+MB4O 1.750E+13 0.01 -1.510E+03 REV/ 8.958E+14 -0.39 2.931E+04 / NC3H7O2+MBMJ<=>NC3H7O+MBMO 1.743E+13 0.02 -1.510E+03 REV/ 1.643E+15 -0.42 4.072E+04 / MB4O<=>CH2O+MP3J 7.041E+17 -1.34 2.011E+04 REV/ 1.500E+11 0.00 1.190E+04 / MB3O<=>CH3CHO+ME2J 3.193E+20 -2.22 1.734E+04 REV/ 1.500E+11 0.00 1.190E+04 / MB2O<=>ME2*O+C2H5 1.880E+21 -1.97 2.841E+04 REV/ 1.500E+11 0.00 1.190E+04 / MBMO<=>MBM*O+H 1.329E+13 0.13 2.815E+04 REV/ 6.628E+09 1.11 4.226E+03 / MB4O<=>MB4*O+H 3.591E+14 -0.01 2.297E+04 REV/ 6.628E+09 1.11 4.226E+03 / MB3O<=>MP3*O+CH3 4.402E+17 -1.23 1.974E+04 REV/ 1.500E+11 0.00 1.190E+04 / MB2O<=>C2H5CHO+CH3OCO 2.671E+24 -3.15 2.366E+04 REV/ 1.500E+11 0.00 1.190E+04 / MBMO<=>CH2O+BAOJ 1.273E+20 -2.04 4.506E+04 REV/ 1.500E+11 0.00 1.190E+04 / CHOOCO<=>OCHO+CO 7.371E+15 -1.38 1.420E+04 REV/ 1.500E+11 0.00 3.000E+03 / MP2D+CH3<=>C2H3CO+CH2O+CH4 4.520E-01 3.65 7.154E+03 REV/ 0.000E+00 0.00 0.000E+00 / MP2D+H<=>C2H3CO+CH2O+H2 9.400E+04 2.75 6.280E+03 REV/ 0.000E+00 0.00 0.000E+00 / MP2D+O<=>C2H3CO+CH2O+OH 9.650E+04 2.68 3.716E+03 REV/ 0.000E+00 0.00 0.000E+00 / MP2D+OH<=>C2H3CO+CH2O+H2O 5.250E+09 0.97 1.590E+03 REV/ 0.000E+00 0.00 0.000E+00 / MP2D+HO2<=>C2H3CO+CH2O+H2O2 4.040E+04 2.50 1.669E+04 REV/ 0.000E+00 0.00 0.000E+00 / MB2D+O<=>CH3OCO+CH3CHCHO 5.010E+07 1.76 7.600E+01 REV/ 7.808E+02 2.97 2.250E+04 / DUP END